首页|LiMn0.6Fe0.4PO4正极材料的制备与性能分析

LiMn0.6Fe0.4PO4正极材料的制备与性能分析

扫码查看
LiMn1-xFexPO4具有成本低廉、环境友好、能量密度高和稳定性高等优点,在锂离子电池中具有良好的应用前景.目前在制备LiMn1-xFexPO4的各种方法中,液相法制得的产品性能较佳.文中以葡萄糖为碳源,通过氢氧化物共沉淀法和球磨法,利用固相反应制备了碳包覆的LiMn0.6Fe0.4PO4纳米颗粒.经过电化学测试,LiMn0.6Fe0.4PO4在0.3 C、0.5 C、1 C和2 C倍率下的放电比容量约为127 mAh/g、119 mAh/g、104 mAh/g和82 mAh/g,且在1C和2C下循环200圈后的容量保持率均接近100%,该材料具有良好的倍率性能和循环稳定性.
Synthesis and performance analysis of LiMn0.6Fe0.4PO4 cathode material
LiMn1-xFexPO4 with the advantages of low cost,environmental friendliness,high energy density as well as high stability,has a promising application for lithium-ion batteries.Among various methods for preparing LiMn1-xFexPO4,the solution method is suitable for its synthesis because of the better performance of the product.In this paper,the glucose was used as carbon source to obtain carbon-coated LiMn0.6 Fe0.4 PO4 nanoparticles by solid-phase reaction through hydroxide co-precipitation method and ball-milling method.The electrochemical testing results showed that the LiMn0.6 Fe0.4 PO4/C composite could deliver discharge capacities of 127 mAh/g,119 mAh/g,104 mAh/g and 82 mAh/g at 0.3 C,0.5 C,1 C and 2 C rate,respectively.In addition,the capacity retention was nearly 100%after 200 cycles at 1 C and 2 C,showing the excellent rate capability and cyclability.

lithium manganese iron phosphateco-precipitation methodcathode materiallithium-ion batteriescarbon coating

王洪波、郭乙成、陈昊、张贵朝

展开 >

河南工学院材料科学与工程学院,河南新乡 453003

磷酸锰铁锂 共沉淀法 正极材料 锂离子电池 碳包覆

河南省高等学校重点科研项目河南工学院博士科研启动基金

20B150005KQ1849

2024

电池工业
中国电池工业协会,轻工业化学电源研究所

电池工业

影响因子:0.287
ISSN:1008-7923
年,卷(期):2024.28(4)