首页|锌空气电池MnO2正极改性研究进展

锌空气电池MnO2正极改性研究进展

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锌空气电池MnO2正极材料因其具有较高的工作电压和较低的成本而备受关注,但该材料导电性差,在充放电过程中易发生结构坍塌,导致其比容量较低和循环稳定性较差,这些问题严重制约了锌空气电池的发展.本文通过调研相关文献,综述了提高MnO2正极材料电导率和循环稳定性的策略,重点介绍了 MnO2形貌调控、离子掺杂、材料复合和其他调控方法等改性策略.通过分析不同晶体结构的MnO2正极材料及掺杂和材料复合对其电导率和循环稳定性的影响,提供了提高MnO2正极材料性能的思路.最后,对未来高性能锌空气电池中MnO2正极材料的发展进行了展望.
Research progress on the modification of manganese dioxide cathode in zinc-air batteries
The MnO2 cathode material of zinc-air batteries has attracted great attention due to its high working voltage and low manufacturing cost.However,it suffers from poor conductivity and structural collapse during charge and discharge processes,leading to low specific capacity and poor cycling stability.In this article,we reviewed the strategies to improve the conductivity and cycling stability of MnO2 cathode materials,including structural regulation,doping modification,material composites,and other control methods.We also analyzed the influence of different crystal structures,doping,and material composites on the conductivity and cycling stability of MnO2 cathode materials,providing insights for enhancing their performance.Finally,we provided prospects for the future development of MnO2 cathode materials in high-performance zinc-air batteries,suggesting the synergistic combination of various improvement strategies.

zinc-air batteriesMnO2modification strategieselectrocatalystoxygen reduction reaction

杨东、黄幼菊、冯哲、陈志豪

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珠海科技学院应用化学与材料学院,广东珠海 519041

锌空气电池 MnO2 改性策略 电催化剂 氧还原反应

2024

电池工业
中国电池工业协会,轻工业化学电源研究所

电池工业

影响因子:0.287
ISSN:1008-7923
年,卷(期):2024.28(5)