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甲烷化催化剂失活原因分析及处理对策

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某炼化企业煤焦制氢装置因酸脱单元变换气冷却器腐蚀泄漏,导致下游甲烷化单元催化剂逐步失活.从甲烷化催化剂中毒、积碳、活性组分烧结、流失等失活机理分析甲烷化催化剂失活的原因,提出了变更泄漏设备的材质、降低粗氢气中硫含量、适当提高床层温度等措施,进一步延长甲烷化催化剂的使用寿命.
DISCUSSION ON DEACTIVATION OF METHANATION CATALYST
The corrosion leakage of shift gas cooler in acitic gas removal unit in a coal char hydrogen production plant led to the gradual deactivation of the downstream methanation catalyst. This paper analyzed the reasons of catalyst deactivation from the mechanism of catalyst poisoning, carbon deposition, sintering and catalyst loss, and presented the measures to extend the life of the catalyst, such as changing the material of the equipment, reducing sulfur content in raw hydrogen, and raise the bed temperature etc.

coal char hydrogen productionmethanation catalystpoisoningoperation lifedeactivation

赵世斌

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中国石化镇海炼化分公司,浙江宁波 315207

煤焦制氢装置 甲烷化催化剂 中毒 使用寿命 失活

2024

大氮肥
中国石化集团宁波技术研究院

大氮肥

影响因子:0.15
ISSN:1002-5782
年,卷(期):2024.47(2)
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