首页|金刚石中的硫化物包裹体:对地球早期演化及古老地壳物质再循环的示踪

金刚石中的硫化物包裹体:对地球早期演化及古老地壳物质再循环的示踪

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地球早期演化及古老地壳物质再循环是地球科学领域研究的热点和难点问题之一.研究该科学问题的关键在于能否找到直接的物质记录.而形成于新太古代到中生代,主要分布于克拉通岩石圈地幔(可以延伸到过渡带甚至下地幔)的金刚石具有生长时间跨度长,分布范围广的特点.金刚石及其生长过程中所捕获的地幔矿物成为其最理想的研究载体.其中,金刚石生长过程中捕获的俯冲沉积硫化物和地幔原始硫化物,为与金刚石形成有关的克拉通早期形成与演化过程以及超大陆旋回背景下的俯冲事件提供了来自年代学及同位素地球化学的独特指示.近二十年来的研究表明:①硫化物包裹体主要有地幔原生来源和古老壳源俯冲物质来源两大类;②硫化物包裹体的Re-Os等时线年龄限定了金刚石的形成时代,大量定年工作为早期板块构造的启动时间提供了关键性证据;③硫化物包裹体的非质量分馏S同位素(MIF-S)记录了大氧化事件发生前贫氧大气环境下的壳源沉积硫化物信号,为建立地球早期硫循环模型和板块构造过程提供了重要依据.此外,本文在综合分析国际金刚石硫化物包裹体研究成果的基础上,提出了当前研究仍存在的问题以及对我国金刚石硫化物包裹体研究的思考.
Sulfide Inclusions in Diamonds:Tracing the Early Evolution of Earth and the Recycling of Ancient Crustal Materials
The early evolution of Earth and the recycling of ancient crustal materials remain pivotal and challenging areas of geoscience research.Addressing these issues requires direct material records that capture key geological processes.Diamonds,spanning a formation age range from the Late Archean to the Mesozoic and predominantly hosted in the cratonic lithospheric mantle(extending into the mantle transition zone and even the lower mantle),represent unparalleled records owing to their long growth history and extensive spatial distribution.The sulfide inclusions encapsulated during diamond growth,including subducted sedimentary sulfides and mantle-derived primary sulfides,provide invaluable geochronological and isotopic constraints on the formation and evolution of cratons,as well as on subduction events within the framework of supercontinent cycles.Studies in the past two decades have yielded critical insights:(1)sulfide inclusions are broadly classified into mantle-derived primary sulfides and subducted crustal sulfides;(2)Re-Os isotopic systematics of sulfide inclusions offer robust age constraints on diamond formation,providing essential evidence for the initiation of early plate tectonics;and(3)Mass-Independent Sulfur isotope Fractionation(MIF-S)in sulfide inclusions preserves signals of crustal-derived sedimentary sulfides formed under anoxic atmospheric conditions prior to the Great Oxidation Event,offering significant implications for reconstructing Earth's early sulfur cycle and tectonic regimes.This review summarizes advances in the study of sulfide inclusions in diamonds,identifies outstanding challenges,and provides perspectives on the advancing research in this field,with an emphasis on the underexplored diamond sulfide inclusions from China.

diamondsulfide inclusionsRe-Os datingmass independent sulfur isotope fractionationrecycling of ancient crustal materialsplate tectonics

丁永康、丘志力、邓小芹、马瑛、孙媛

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中山大学 地球科学与工程学院/广东省地球动力作用与地质灾害重点实验室,广东 珠海 519082

桂林理工大学 材料科学与工程学院,广西 桂林 541000

广东省科学院微生物研究所,广东 广州 510070

国检中心深圳珠宝检验实验室有限公司,广东 深圳 518001

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金刚石 硫化物包裹体 Re-Os定年 非质量分馏S同位素 古老地壳物质再循环 板块构造

2025

大地构造与成矿学
中国科学院广州地球化学研究所

大地构造与成矿学

北大核心
影响因子:1.45
ISSN:1001-1552
年,卷(期):2025.49(1)