电镀与精饰2024,Vol.46Issue(2) :52-61.DOI:10.3969/j.issn.1001-3849.2024.02.008

搅拌摩擦加工对AZ31镁合金腐蚀行为的影响

Effect of friction stir processing on corrosion behavior of AZ31 magnesium alloy

刘刚 周元森 张林 闫基森 张玺 解芳
电镀与精饰2024,Vol.46Issue(2) :52-61.DOI:10.3969/j.issn.1001-3849.2024.02.008

搅拌摩擦加工对AZ31镁合金腐蚀行为的影响

Effect of friction stir processing on corrosion behavior of AZ31 magnesium alloy

刘刚 1周元森 1张林 2闫基森 1张玺 1解芳1
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作者信息

  • 1. 南阳理工学院 河南省增材制造航空材料工程研究中心,河南 南阳 473004;南阳理工学院南阳市增材制造技术与装备重点试验室,河南 南阳 473004
  • 2. 洛阳轴承研究所有限公司,河南 洛阳 471039
  • 折叠

摘要

为了探究搅拌摩擦加工对AZ31镁合金腐蚀性能的影响,采用体视镜、光学显微镜、接触角测量仪、电化学工作站等设备研究了AZ31母材与不同工艺参数下FSP-AZ31在3.5 wt.%NaCl溶液中的腐蚀行为.结果表明:在转速800~1200 r/min、加工速度80~120 mm/min范围内,FSP-AZ31与母材腐蚀机制均为点蚀.与母材相比,FSP-AZ31点蚀程度较轻,自腐蚀电流密度减小,阻抗增大,FSP均能够提高AZ31镁合金的耐腐蚀性能.当加工速度为 100 mm/min时,随着旋转速度增大,FSP-AZ31自腐蚀电流密度不断减小,耐腐蚀性能不断提升.试样在旋转速度为1200 r/min时自腐蚀电流密度达到最小值9.2×10-5 A·cm-2.当旋转速度为1000 r/min时,随着加工速度减小,FSP-AZ31自腐蚀电流密度不断减小,耐腐蚀性能不断提升.在加工速度为80 mm/min时试样的自腐蚀电流密度达到最小,其值为7.6×10-5 A·cm-2.相比AZ31镁合金,1000 r/min和80 mm/min条件下FSP-AZ31的接触角由29.703 °上升至58.448 °.

Abstract

In order to investigate the effect of friction stir processing on the corrosion performance of AZ31 magnesium alloy,the corrosion behavior of AZ31 base material and FSP-AZ31 under different process parameters in 3.5 wt.%sodium chloride solution was studied using stereoscopy,optical micros-copy,contact angle measurement,electrochemical workstation and other equipments.The results show that the corrosion mechanism of FSP-AZ31 and the base metal is pitting corrosion in the range of rotat-ing speed 800-1200 r/min and processing speed 80-120 mm/min.Compared with the base metal,FSP-AZ31 has a lighter degree of pitting corrosion,the self-corrosion current density is reduced,the impedance is increased,and FSP can improve the corrosion resistance of AZ31 magnesium alloy.When the processing speed is 100 mm/min,as the rotation speed increases,the self-corrosion current density of FSP-AZ31 is continuously decreased,and the performance of corrosion resistance is continuously improved.When the rotation speed is 1200 r/min,the self-corrosion current density of the sample reaches the minimum value of 9.2×10-5 A·cm-2.When the rotation speed is 1000 r/min,as the pro-cessing speed decreases,the self-corrosion current density of FSP-AZ31 is continuously decreased,and the performance of corrosion resistance is continuously improved.When the processing speed is 80 mm/min,the corrosion current density of the sample reaches the minimum,with a value of 7.6×10-5 A·cm-2.Compared to AZ31 magnesium alloy,the contact angle of FSP-AZ31 is increased from 29.703 ° to 58.448 ° under 1000 r/min and 80 mm/min.

关键词

搅拌摩擦加工/AZ31镁合金/工艺参数/接触角/耐腐蚀性能

Key words

friction stir processing/AZ31 magnesium alloy/process parameters/contact angle/corrosion performance

引用本文复制引用

基金项目

国家自然科学基金青年项目(51701026)

河南省重点研发与推广专项(科技攻关)(232102230049)

河南省重点研发与推广专项(科技攻关)(232102221022)

南阳理工学院交叉科学研究项目(520067)

出版年

2024
电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
参考文献量17
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