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搅拌摩擦加工对AZ31镁合金腐蚀行为的影响

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为了探究搅拌摩擦加工对AZ31镁合金腐蚀性能的影响,采用体视镜、光学显微镜、接触角测量仪、电化学工作站等设备研究了AZ31母材与不同工艺参数下FSP-AZ31在3.5 wt.%NaCl溶液中的腐蚀行为.结果表明:在转速800~1200 r/min、加工速度80~120 mm/min范围内,FSP-AZ31与母材腐蚀机制均为点蚀.与母材相比,FSP-AZ31点蚀程度较轻,自腐蚀电流密度减小,阻抗增大,FSP均能够提高AZ31镁合金的耐腐蚀性能.当加工速度为 100 mm/min时,随着旋转速度增大,FSP-AZ31自腐蚀电流密度不断减小,耐腐蚀性能不断提升.试样在旋转速度为1200 r/min时自腐蚀电流密度达到最小值9.2×10-5 A·cm-2.当旋转速度为1000 r/min时,随着加工速度减小,FSP-AZ31自腐蚀电流密度不断减小,耐腐蚀性能不断提升.在加工速度为80 mm/min时试样的自腐蚀电流密度达到最小,其值为7.6×10-5 A·cm-2.相比AZ31镁合金,1000 r/min和80 mm/min条件下FSP-AZ31的接触角由29.703 °上升至58.448 °.
Effect of friction stir processing on corrosion behavior of AZ31 magnesium alloy
In order to investigate the effect of friction stir processing on the corrosion performance of AZ31 magnesium alloy,the corrosion behavior of AZ31 base material and FSP-AZ31 under different process parameters in 3.5 wt.%sodium chloride solution was studied using stereoscopy,optical micros-copy,contact angle measurement,electrochemical workstation and other equipments.The results show that the corrosion mechanism of FSP-AZ31 and the base metal is pitting corrosion in the range of rotat-ing speed 800-1200 r/min and processing speed 80-120 mm/min.Compared with the base metal,FSP-AZ31 has a lighter degree of pitting corrosion,the self-corrosion current density is reduced,the impedance is increased,and FSP can improve the corrosion resistance of AZ31 magnesium alloy.When the processing speed is 100 mm/min,as the rotation speed increases,the self-corrosion current density of FSP-AZ31 is continuously decreased,and the performance of corrosion resistance is continuously improved.When the rotation speed is 1200 r/min,the self-corrosion current density of the sample reaches the minimum value of 9.2×10-5 A·cm-2.When the rotation speed is 1000 r/min,as the pro-cessing speed decreases,the self-corrosion current density of FSP-AZ31 is continuously decreased,and the performance of corrosion resistance is continuously improved.When the processing speed is 80 mm/min,the corrosion current density of the sample reaches the minimum,with a value of 7.6×10-5 A·cm-2.Compared to AZ31 magnesium alloy,the contact angle of FSP-AZ31 is increased from 29.703 ° to 58.448 ° under 1000 r/min and 80 mm/min.

friction stir processingAZ31 magnesium alloyprocess parameterscontact anglecorrosion performance

刘刚、周元森、张林、闫基森、张玺、解芳

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南阳理工学院 河南省增材制造航空材料工程研究中心,河南 南阳 473004

南阳理工学院南阳市增材制造技术与装备重点试验室,河南 南阳 473004

洛阳轴承研究所有限公司,河南 洛阳 471039

搅拌摩擦加工 AZ31镁合金 工艺参数 接触角 耐腐蚀性能

国家自然科学基金青年项目河南省重点研发与推广专项(科技攻关)河南省重点研发与推广专项(科技攻关)南阳理工学院交叉科学研究项目

51701026232102230049232102221022520067

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(2)
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