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石墨烯添加剂与电流密度对铝锂合金阳极氧化膜层耐蚀性能的影响

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本文以Al-Li-Cu-Mg合金为研究对象,在混酸电解液体系下进行阳极氧化处理,制备不同电流密度以及石墨烯掺入后的氧化膜.通过SEM、XRD、EDS等分析测试手段分析了各参数下膜层的表面与截面形貌、元素、物相组成等,并通过电化学工作站等仪器分别分析了膜层的耐蚀等性能.研究不同电流大小与石墨烯掺入后对膜层性能的影响机制.结果表明:电流密度的增加会使得材料膜层的厚度先增后减、缺陷增加,耐蚀性能先增后减,阳极氧化膜耐蚀性能最佳电流密度为 15 A/dm2.同时石墨烯的掺入会降低膜层耐蚀性,阳极氧化膜腐蚀电流密度为 4.898×10-7 A·cm-2.
Effect of graphene additive and current density on corrosion resistance of anodized coatings on aluminium-lithium alloys
Al-Li-Cu-Mg alloy was anodized in mixed acid electrolyte system to prepare oxide films with different current densities and graphene infiltration.The surface and cross-sectional morphology,elemental composition,and phase composition of the film layer under various parameters were analyzed using SEM,XRD,EDS and other analysis and testing methods.The corrosion resistance and other properties of the film layer were also analyzed using electrochemical workstations and other instru-ments.The influence mechanism of different current and graphene penetration on the film properties was studied.The experimental results show that an increase in current density will first increase and then decrease the thickness of the material film layer,increase defects,and increase and then decrease the corrosion resistance.The optimal current density for corrosion resistance of anodic oxide film is 15 A/dm2.At the same time,the inclusion of graphene will reduce the corrosion resistance of the film,and the corrosion current density of the anodized film is 4.898×10-7 A·cm-2.

aluminium-lithium alloysanodizinggraphenecorrosion resistance

邓名洋、李瑞金、张南瑞、张超杰

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黑龙江科技大学 材料科学与工程学院,黑龙江 哈尔滨 150022

中国建筑第三工程局第三建设工程有限责任公司,湖北 武汉 430070

浙江水利水电学院 机械与汽车工程学院,浙江 杭州 310018

铝锂合金 阳极氧化 石墨烯 耐蚀性能

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(2)
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