首页|A356铝合金的表面改性与耐磨及耐蚀性能研究

A356铝合金的表面改性与耐磨及耐蚀性能研究

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为了提升A356铝合金的表面耐磨耐蚀性能,采用等离子喷涂的方法在A356铝合金基体表面制备了4种高熵合金涂层(FeCoCrNi和FeCoCrNi+Mn/Cu/Ti),对比分析了各等离子喷涂涂层的物相组成、显微形貌、硬度、耐磨和耐蚀性能.结果表明4种等离子喷涂涂层中都可见面心立方固溶体和氧化物的衍射峰.在FeCoCrNi中加入Cu/Ti后,涂层中还出现了Cu/Ti的衍射峰.4种等离子喷涂涂层厚度都介于210~300µm,涂层与基体界面以机械结合为主.4种等离子喷涂涂层的硬度、平均摩擦系数都高于A356铝合金基体,磨损率从低至高顺序为:FeCoCrNi(涂层Ⅰ)<FeCoCrNiTi(涂层Ⅳ)<FeCoCrNiMn(涂层Ⅱ)<FeCoCrNiCu(涂层Ⅲ)<基体.相较A356铝合金基体,涂层的腐蚀电位发生正向移动,腐蚀电流密度和点蚀电位减小,Nyquist圆弧半径、阻抗模值|Z|0.01 Hz和电荷转移电阻Rct增大.4种等离子喷涂涂层的耐蚀性能都优于A356铝合金基体,且涂层Ⅳ的耐腐蚀性能最好.
Study on surface modification and wear and corrosion resistance of A356 aluminum alloy
In order to improve the surface wear resistance and corrosion resistance of A356 aluminum alloy, four kinds of high entropy alloy coatings (FeCoCrNi and FeCoCrNi+Mn/Cu/Ti) were prepared on the surface of A356 aluminum alloy by plasma spraying. The phase composition, microstructure, hardness, wear resistance and corrosion resistance of plasma spraying coatings were compared and ana-lyzed. The results show that the four kinds of plasma spraying coatings all have the diffraction peaks of face centered cubic solid solution and oxide, when the element Cu/Ti is added to FeCoCrNi, the Cu/Ti diffraction peaks also appear in the coatings. The thickness of the four plasma spraying coatings is be-tween 210 µm and 300 µm, and the interface between the coating and the substrate is mainly mechani-cal. The hardness and average friction coefficient of the four plasma spraying coatings are higher than that of A356 aluminum alloy substrate, the order of wear rate from low to high is: FeCoCrNi (coating Ⅰ)<FeCoCrNiTi(coating Ⅳ)<FeCoCrNiMn(coating Ⅱ)<FeCoCrNiCu(coating Ⅲ)<substrate. Com-pared with A356 aluminum alloy substrate, the corrosion potential of coating shifted forward, and the corrosion current density and pitting potential decreased, the Nyquist arc radius, impedance modulus |Z|0.01 Hz and charge transfer resistance Rct increased. The corrosion resistance of the four plasma spraying coatings is better than that of A356 aluminum alloy substrate, and the corrosion resistance of coating Ⅳ is the best.

A356 aluminum alloyplasma sprayingFeCoCrNi coatingsurface modificationwear resistancecorrosion resistance

禹露、许婄鑫、罗志翔

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河南地矿职业学院智能制造学院,河南郑州 451464

郑州大学材料科学与工程学院,河南郑州 450001

A356铝合金 等离子喷涂 FeCoCrNi涂层 表面改性 耐磨性 耐腐蚀性

河南省杰出人才创新基金河南科技智库调研课题

182102610014HNKJZK-2024-39B

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(4)
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