首页|基于碳纳米管涂装的超疏水表面及性能研究

基于碳纳米管涂装的超疏水表面及性能研究

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为了实现绿色环保的方式制备超疏水表面,采用碳纳米管(CNT)涂装与SLM-3D打印结合的方式制备金属基底的超疏水表面.利用扫描电子显微镜和表面成分能谱分析进行表征,发现碳纳米管成功涂装至3D打印的类水稻沟槽结构上,并呈现出团簇结构.碳纳米管团簇与试样表面的沟槽结构形成了两级结构特征,无需氟硅烷等含氟物质修饰便获得超疏水特性,其接触角为153.1°,滚动角为8.2°.对碳纳米管涂装和氟硅烷修饰这两种方式制备的试样表面进行耐腐蚀性能、黏附性能、机械性能等测试.结果表明:碳纳米管涂装的超疏水表面不仅具有优异的耐腐蚀性能,而且表面黏附力极小,仅为23.2 μN.碳纳米管涂装的试样表面经过线性磨损280 cm后,接触角依然在150°以上.采用3D打印结合碳纳米管涂装的超疏水表面抗破坏力强,疏水功能稳定.
Study on superhydrophobic surface and properties based on carbon nanotube coating
In order to prepare superhydrophobic surfaces in a green and environmentally friendly way,the combination of carbon nanotube(CNT)coating and SLM-3D printing was used to prepare superhy-drophobic surfaces on metal substrates.Characterized by scanning electron microscopy and surface composition energy spectrum analysis,it was found that carbon nanotubes were successfully coated on the 3D printed rice-like groove structure and presented a cluster structure.The carbon nanotube clusters and the groove structure on the surface of the sample formed a two-level structural feature,and the superhydrophobic property was obtained without the modification of fluorine-containing substances such as fluorosilicate.The contact angle was 153.1° and the rolling angle was 8.2°.The corrosion resistance,adhesion and mechanical properties of the samples prepared by carbon nanotube coating and fluorosilane modification were tested.The results showed that the superhydrophobic surface coated with carbon nanotubes not only had excellent corrosion resistance but also had a minimal surface adhesion of only 23.2 μN.The contact angle of the sample coated with carbon nanotubes was still above 150° after linear wear of 280 cm.The superhydrophobic surface coated with 3D printing combined with carbon nanotubes had strong damage resistance and stable hydrophobic function.

carbon nanotubesuperhydrophobicSLM-3D printingcharacterization of hydrophobic properties

余金桂、阮赣江、章桥新

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武汉理工大学 机电工程学院,湖北 武汉 430070

碳纳米管 超疏水 SLM-3D打印 疏水性能表征

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(6)
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