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一种结构仿生防污涂料的制备

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仿生防污涂料是通过模拟海洋生物的皮肤和结构,或者提取海洋生物体内的防污物质制备出的防污涂料.本文采用简单盐溶解法,通过模拟软珊瑚上层透明层和下层多孔层的复合结构,以不同方式添加软珊瑚体内的防污化学物质糖精、加巴喷丁和正癸酸,制备了组成不同的仿生防污涂料,并对涂料的防污性能进行了研究.研究结果表明,糖精∶加巴喷丁∶正癸酸为47∶23∶25样品的压缩模量最小,糖精∶加巴喷丁∶正癸酸为42∶33∶25样品和糖精含量为0.01 g的样品压缩模量次之.压缩模量越小,越容易变形.糖精∶加巴喷丁∶正癸酸为47∶23∶25样品的透明层和多孔层的表面能最小,分别为22.2 mJ/m2和16.0 mJ/m2.糖精∶加巴喷丁∶正癸酸为42∶33∶25样品和糖精含量为0.01 g样品的透明层和多孔层的表面能次之,分别为22.7 mJ/m2、22.9 mJ/m2和16.1 mJ/m2、16.5 mJ/m2.表面能越小,疏水性越好,防污性能越好.对样品进行了抗污渍实验和静态抑菌实验,研究表明:和加入单一防污组分的仿生防污涂料相比,将三种防污组分全部加入的仿生防污涂料具有更好的防污效果;加入糖精的样品比加入其它单一防污组分的样品防污效果更好.
Preparation of a structural bionic antifouling coating
The bionic anti-fouling coating is an anti-fouling coating prepared by simulating the skin and structure of marine organisms,or extracting the anti-fouling substances in the body of marine organ-isms.In this paper,the simple salt dissolution method was used to simulate the composite structure of the upper transparent layer and lower porous layer of soft coral.The anti-fouling chemical substances of saccharin,gabapentin and capric acid in soft coral were added in different ways to prepare bionic anti-fouling coatings with different compositions,and the fouling resistance of the coatings was studied.The results showed that the compression modulus of the sample with the ratio of saccharin∶gabapentin∶cap-ric acid of 47∶23∶25 was the smallest,followed by the sample with the ratio of 42∶33∶25 and the sam-ple with 0.01 g saccharin.The smaller the compression modulus,the easier it is to deform.The surface energy of the transparent layer and porous layer of the sample with the ratio of saccharin∶gabapentin∶capric acid of 47∶23∶25 was the smallest,which was 22.2 and 16.0 mJ/m2,respectively.The surface energy of the transparent layer and porous layer of the samples with the ratio of saccharin∶gabapentin∶capric acid of 42∶33∶25 and 0.01 g saccharin was second,which was 22.7,22.9 and 16.1,16.5 mJ/m2,respectively.The smaller the surface energy,the better the hydrophobicity and anti-fouling perfor-mance.The samples were tested for stain resistance and static antibacterial experiments.The research showed that compared with the bionic anti-fouling coatings with single anti-fouling component,the bionic anti-fouling coating with all three anti-fouling components had better anti-fouling effect.The sample with saccharin had better anti-fouling effect than that with other single anti-fouling components.

bionicsantifouling paintsoft coral

高虹、李学田

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沈阳理工大学 环境与化学工程学院,辽宁 沈阳 110159

仿生 防污涂料 软珊瑚

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(7)
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