首页|N,N'-亚甲基双丙烯酰胺与OP-10对Q235钢在1mol/LHCl中的缓蚀作用

N,N'-亚甲基双丙烯酰胺与OP-10对Q235钢在1mol/LHCl中的缓蚀作用

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针对在酸洗工况下金属的腐蚀问题,为解决单一缓蚀剂的成本高、效率低的问题,在N,N'-亚甲基双丙烯酰胺(NN)的最佳缓蚀浓度基础上将其与OP-10复配(N&P),采取失重实验、电化学实验、表面分析和理论模拟的方法,研究了NN和N&P缓蚀剂对Q235钢在1.0 mol/L HCl溶液中的缓蚀性能.结果表明:在30℃条件下,NN的交流阻抗谱、动电位极化曲线和失重实验所得的最佳缓蚀率分别为73.32%、85.57%、77.46%,而将NN与OP-10复配后的缓蚀效率分别提升至92.34%、96.26%、90.14%.量子化学表明:N&P吸附位点主要为OP-10分子中的大Π键和C-O键以及NN分子中的C=O键、C=C键、C-N键,具有较好的协同效应.
Corrosion inhibition of N,N'-methylene bisacrylamide and OP-10 on Q235 steel in 1 mol/L HCL
In order to solve the problem of high cost and low efficiency of a single corrosion inhibitor,N,N'-methylene diacrylamide(NN)was combined with OP-10(N&P)on the basis of the optimal cor-rosion inhibition concentration,weight loss experiment,electrochemical experiment,surface analysis and theoretical simulation were adopted.The corrosion inhibition properties of NN and N&P on Q235 steel in 1.0 mol/L HCl solution were studied.The results show that at 30℃,the optimal corrosion inhibition rates obtained by AC impedance spectrum,potentiodynamic polarization curve and weight loss experiment are 73.32%,85.57%and 77.46%,respectively,while the corrosion inhibition efficien-cy of NN combined with OP-10 is increased to 92.34%,96.26%and 90.14%,respectively.Quantum chemistry shows that the adsorption sites of N&P are mainly the bigπbond and C-O bond in OP-10 molecule and the C=O bond,C=C bond and C-N bond in NN molecule,and N&P has a good synergis-tic effect.

N,N'-methylene bisacrylamideOP-10electrochemistryweight loss experimentcorro-sion inhibition performancequantum chemistry

樊林、王鹏杰、宋昱灏、刘婉颖、梅宗斌、林元华

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西南石油大学 油气藏地质及开发工程国家重点实验室,四川 成都 610500

西南石油大学新能源与材料学院,四川 成都 610500

华宇钻采装备有限公司,四川 泸州 646000

N'N-亚甲基双丙烯酰胺 OP-10 电化学 失重实验 缓蚀性能 量子化学

国家自然科学基金四川省自然科学基金

520742322022NSFSC0028

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(7)
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