电镀与精饰2024,Vol.46Issue(10) :56-66.DOI:10.3969/j.issn.1001-3849.2024.10.009

碳钢表面电镀锌镍/有机富铝复合涂层的制备与性能

Preparation and properties of electroplating zinc-nickel alloy/organic aluminum-rich composite coatings on carbon steel surface

刘建国 金宁 王淼 张博伦 韩力 韩长智 王继文 李庆鹏
电镀与精饰2024,Vol.46Issue(10) :56-66.DOI:10.3969/j.issn.1001-3849.2024.10.009

碳钢表面电镀锌镍/有机富铝复合涂层的制备与性能

Preparation and properties of electroplating zinc-nickel alloy/organic aluminum-rich composite coatings on carbon steel surface

刘建国 1金宁 2王淼 2张博伦 2韩力 2韩长智 3王继文 4李庆鹏5
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作者信息

  • 1. 中国科学院金属研究所,辽宁沈阳 110016
  • 2. 新东北电气集团高压开关有限公司,辽宁沈阳 110027
  • 3. 沈阳市航达科技有限责任公司,辽宁沈阳 110043
  • 4. 沈阳亿航精饰环保有限公司,辽宁沈阳 110180
  • 5. 沈阳化工大学材料科学与工程学院,辽宁沈阳 110142
  • 折叠

摘要

为提高碳钢表面电镀锌镍的防护性能和应用限制,采用电镀锌镍层作为底层,有机富铝涂层作为顶层,设计出一种复合涂层防护体系.采用扫描电镜(SEM)、能谱(EDS)、中性盐雾试验、电化学测试等手段对电镀锌镍/有机富铝复合涂层的表面/截面形貌及耐蚀性进行表征与分析.结果表明:电镀锌镍/有机富铝复合涂层表面光滑平整,无明显缺陷,复合涂层体系界面结合良好,无分层现象,经1500h中性盐雾试验后复合涂层无红锈.复合涂层较单独的电镀锌镍合金层腐蚀电流密度降低了 2个数量级,表现出受控的牺牲阳级作用,并实现了在海洋防护领域的应用.复合涂层有效提升了电镀锌镍层的耐腐蚀性能,拓宽了电镀锌镍层在腐蚀防护领域的应用范围.

Abstract

In order to improve the protection performance and application restrictions of galvanized nickel alloys on the surface of carbon steel,the electroplating zinc-nickel layer was used as the bottom layer,and the organic aluminum coating was used as the top layer to design a composite coating protection system.The surface/section of the surface/section of the composite coating of electroplating nickel/organic aluminum coating and analysis.The surface/cross section morphology and corrosion resistance of Ni/Al composite coatings were characterized and analyzed by means of scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),neutral salt spray test and electrochemical test.The results show that the surface of the organic aluminum coating is smooth and flat,without obvious defects.The composite coating system interface is well-combined and there is no layered phenomenon.After 1500 h neutral salt fog test,the composite coating is not red rust.The corrosion current density of the composite coating is 2 orders lower than that of the single electro Zn-Ni alloy layer,and the composite coating shows excellent protective performance,which will realize the application in the field of Marine protection.The composite coating has a higher corrosion resistance compared to the separate electroplating Zn-Ni alloy layer,which effectively solves the protection limit of electroplating nickel alloys in applications.

关键词

电镀锌镍/有机富铝/复合涂层/耐蚀性

Key words

electroplating zinc-nickel alloys/organic aluminum-rich/composite coating/corrosion resistance

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出版年

2024
电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
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