首页|Cr12MoV模具钢电沉积不同Co基镀层的抗磨损性能研究

Cr12MoV模具钢电沉积不同Co基镀层的抗磨损性能研究

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为有效提高Cr12MoV模具钢的抗磨损性能,采用电沉积工艺在Cr12MoV模具钢表面制备Co-W合金镀层、Co-W/ZrO2复合镀层、Co-W/MoS2复合镀层和Co-W/ZrO2+MoS2复合镀层.分析了不同Co基镀层的形貌特征、成分和物相结构,并检测了不同Co基镀层的厚度、硬度和抗磨损性能.结果表明:Co-W合金镀层、Co-W/ZrO2复合镀层、Co-W/MoS2复合镀层和Co-W/ZrO2+MoS2复合镀层的形貌特征存在差异,平均晶粒尺寸依次减小,硬度依次增大,抗磨损性能依次增强;但不同Co基镀层的厚度基本相同,并且都呈现Co3W相(200)晶面择优取向.ZrO2颗粒和MoS2颗粒共同参与电沉积过程起到明显的细晶强化作用,还可能引起晶格畸变,促进形成晶粒细小(平均晶粒尺寸为54.2nm)、结构致密的Co-W/ZrO2+MoS2复合镀层,具有高硬度(543.2HV)以及更强的抗塑性变形能力和抗刮擦损伤能力,其抗磨损性能明显好于Co-W合金镀层、Co-W/ZrO2复合镀层、Co-W/MoS2复合镀层.Co-W/ZrO2+MoS2复合镀层作为功能性镀层能有效减轻Cr12MoV模具钢表面磨损.
Anti-wear performance of different Co-based coatings electrodeposited on Cr12MoV die steel
Co-W alloy coating,Co-W/ZrO2 composite coating,Co-W/MoS2 composite coating and Co-W/ZrO2+MoS2 composite coating were prepared on the surface of Cr12MoV die steel by electrodeposition in order to effectively improve the anti-wear performance of Cr12MoV die steel.The morphology characteristics,composition and phase structure of different Co-based coatings were analyzed,and the thickness,hardness and anti-wear performance of different Co-based coatings were tested.The results show that the morphology characteristics of Co-W alloy coating,Co-W/ZrO2 composite coating,Co-W/MoS2 composite coating and Co-W/ZrO2+MoS2 composite coating are different,the average grain size decreases sequentially,the hardness increases sequentially and the anti-wear performance improves sequentially.However,the thickness of different Co-based coatings is similar,and all show the Co3W(200)crystal face preferred orientation.ZrO2 particles and MoS2 particles participate in electrodeposition can significantly refine grains,and may also cause lattice distortion,and promote the formation of dense Co-W/ZrO2+MoS2 composite coating with fine grains(average grain size is 54.2 nm),high hardness(543.2 HV)and stronger resistance to plastic deformation and scratch damage.The anti-wear performance of Co-W/ZrO2+MoS2 composite coating is obviously better than that of Co-W alloy coating,Co-W/ZrO2 composite coating and Co-W/MoS2 composite coating.Co-W/ZrO2+MoS2 composite coating can be used as a functional coating,which can effectively reduce the surface wear of Cr12MoV die steel.

anti-wear performanceelectrodepositionCo-W alloy coatingCo-W/ZrO2 composite coatingCo-W/MoS2 composite coatingCo-W/ZrO2+MoS2 composite coating

孙艳、任伟和

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忻州职业技术学院机电系,山西忻州 034000

河北工程技术学院,河北石家庄 050091

抗磨损性能 电沉积 Co-W合金镀层 Co-W/ZrO2复合镀层 Co-W/MoS2复合镀层 Co-W/ZrO2+MoS2复合镀层

2024

电镀与精饰
天津市电镀工程学会

电镀与精饰

CSTPCD北大核心
影响因子:0.522
ISSN:1001-3849
年,卷(期):2024.46(12)