电镀与涂饰2024,Vol.43Issue(2) :53-61.DOI:10.19289/j.1004-227x.2024.02.007

基于超快激光定域去除的Cu/Ag复合金属网格透明电极性能优化研究

Study on performance optimization of transparent Cu/Ag composite metal mesh electrode based on localized removal with ultrafast laser

王轶伦 李双双 李保家
电镀与涂饰2024,Vol.43Issue(2) :53-61.DOI:10.19289/j.1004-227x.2024.02.007

基于超快激光定域去除的Cu/Ag复合金属网格透明电极性能优化研究

Study on performance optimization of transparent Cu/Ag composite metal mesh electrode based on localized removal with ultrafast laser

王轶伦 1李双双 2李保家3
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作者信息

  • 1. 常州大学机械与轨道交通学院,江苏 常州 213164;江苏大学机械工程学院,江苏 镇江 212013;新誉集团有限公司,江苏 常州 213166
  • 2. 江苏大学机械工程学院,江苏 镇江 212013;常州工程职业技术学院智能制造学院,江苏 常州 213164
  • 3. 江苏大学材料科学与工程学院,江苏 镇江 212013
  • 折叠

摘要

[目的]Ag网格透明电极方块电阻低,但反射率高.[方法]在钠钙玻璃基底表面利用等离子射频磁控溅射沉积Cu/Ag复合金属薄膜,然后采用飞秒脉冲激光定域去除金属层,获得 Cu/Ag 复合金属网格透明电极.分析了激光能量密度、激光扫描速率和激光扫描线重叠率对电极材料去除的影响机制.[结果]在激光能量密度1.4 J/cm2、激光扫描速率300 mm/s和激光扫描线重叠率70%的工艺参数下获得了综合光电性能最为出色的Cu/Ag复合金属网格透明电极,其平均透光率为87.58%,方块电阻为2.15 Ω,品质因子为1.235×10-1 Ω-1.[结论]该电极的综合性能与传统商用ITO(掺锡氧化铟)透明电极相比有巨大提升.

Abstract

[Introduction]The transparent Ag mesh electrode has low sheet resistance but high reflectivity.[Method]A Cu/Ag composite metal film was deposited on the surface of soda-lime glass by plasma radio frequency(RF)magnetron sputtering,and then locally removed by femtosecond pulsed laser,forming a transparent Cu/Ag composite metal mesh electrode.The effects of laser fluence,laser scanning speed,and laser scanning line overlap ratio on the removal of electrode material were discussed.[Result]The transparent Cu/Ag composite metal mesh electrode fabricated at laser fluence 1.4 J/cm2,laser scanning speed 300 mm/s,and laser scanning line overlap ratio 70%exhibited an average optical transmittance of 87.58%,a sheet resistance of 2.15 Ω,and a figure of merit of 1.235×10-1 Ω-1,showing the best photoelectric properties.[Conclusion]The comprehensive performance of the transparent Cu/Ag composite metal mesh electrode is much better than that of the commercial ITO(indium tin oxide)transparent electrode.

关键词

金属网格/超快激光/定域去除/透明电极/光电性能

Key words

metal mesh/ultrafast laser/localization removal/transparent electrode/photoelectric property

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基金项目

常州大学科研启动经费项目(ZMF21020357)

出版年

2024
电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
参考文献量18
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