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低温液体氧氮化对奥氏体不锈钢磨损行为的影响

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[目的]奥氏体不锈钢被广泛用于制造各种航空电子装备零部件,但其硬度和耐磨性欠佳.[方法]采用低温液体氧氮化技术对 304 奥氏体不锈钢进行表面改性处理.采用扫描电子显微镜、透射电子显微镜、维氏硬度计等分析了所得复合改性层的微观组织和截面显微硬度分布,通过摩擦磨损试验探究了表面改性层的耐磨性.[结果]低温液体氧氮化表面改性层由外侧致密的Fe3O4相和内侧富氮S相构成.S相是含氮过饱和固溶体,含有大量位错、层错和孪晶,因此硬度较高.载荷和温度会影响不锈钢样品的磨损行为,温度升高和载荷增大都会使 304 奥氏体不锈钢样品和低温液体氧氮化样品的平均摩擦因数轻微下降,磨损体积损失增大.不过低温液体氧氮化处理能够缩短 304 奥氏体不锈钢样品初始磨损阶段的持续时间,使其在载荷 10 N、温度 200 ℃条件下的最大磨损体积损失由 1.086 mm3 降至 0.144 mm3.[结论]低温液体氧氮化处理能够显著提高304奥氏体不锈钢的耐磨性.
Effect of low-temperature liquid oxy-nitriding on wear behavior of austenitic stainless steel
[Introduction]Austenitic stainless steels are widely used in the manufacturing of various avionic components,but their hardness and wear resistance are not good.[Method]The surface modification of 304 austenitic stainless steel was carried out by low-temperature liquid oxy-nitriding(LTON).The microstructure and microhardness distribution along the cross-section of the LTON layer were characterized by using scanning electron microscope,transmission electron microscope,and Vickers hardness tester.The wear resistance of the modified layer was studied by friction and wear test.[Result]The low-temperature liquid oxy-nitriding layer was composed of the outer compact Fe3O4 phase and the inner nitrogen-rich S-phase.The S-phase is a kind of supersaturated solid solution containing nitrogen and plenty of dislocations,stacking faults,and twin crystals,so it has high hardness.The temperature and load during the friction and wear test affected the wear behavior of 304 austenitic stainless steel.Both the increase in temperature and load led to a slight decrease in the average friction coefficient of 304 austenitic stainless steel and an increase in its wear volume loss,no matter whether it was treated by LTON or not.After being treated by LTON,the duration of the initial wear stage of 304 austenitic stainless steel was shortened,and its maximum wear volume loss was decreased from 1.086 mm3 to 0.144 mm3 under a load of 10 N at 200℃.[Conclusion]The wear resistance of 304 austenitic stainless steel can be significantly improved by LTON.

austenitic stainless steellow-temperature liquid oxy-nitridingmicrostructurewear behavior

李龙义、杨涛、樊勋、陈波、王均、王天石

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中国电子科技集团公司第二十九研究所,四川 成都 610036

成都四威高科技产业园有限公司,四川 成都 611730

四川大学机械工程学院,四川 成都 610064

奥氏体不锈钢 低温液体氧氮化 微观组织 磨损行为

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(3)
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