首页|钝化处理对0Cr17Ni4Cu4Nb不锈钢在西沙群岛海洋大气环境下耐腐蚀性能的影响

钝化处理对0Cr17Ni4Cu4Nb不锈钢在西沙群岛海洋大气环境下耐腐蚀性能的影响

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[目的]研究未钝化和钝化处理的0Cr17Ni4Cu4Nb不锈钢在西沙海洋大气环境下暴露1年的腐蚀行为.[方法]采用扫描电镜(SEM)、能谱仪(EDS)、视频显微镜(VM)、X射线衍射仪(XRD)等仪器研究了未钝化和钝化 0Cr17Ni4Cu4Nb不锈钢腐蚀后的表面形貌及腐蚀产物的成分.[结果]在海洋大气环境下暴露一定时间后,未钝化和钝化处理的0Cr17Ni4Cu4Nb 不锈钢表面均发生了腐蚀,且以点蚀为主,腐蚀质量损失随时间变化的曲线符合幂函数规律,腐蚀产物的主要成分为β-FeOOH.对比腐蚀产物覆盖面积和腐蚀坑深度可知,钝化处理能够提高0Cr17Ni4Cu4Nb不锈钢的耐腐蚀性能,但在西沙海洋大气环境下服役时不能提供长期保护.[结论]应探索新的防护手段来提高 0Cr17Ni4Cu4Nb 不锈钢在海洋大气环境中的耐腐蚀性能.
Effect of passivation on anticorrosion property of 0Cr17Ni4Cu4Nb stainless steel in marine atmosphere of Xisha Islands
[Introduction]The corrosion behaviors of unpassivated and passivated 0Cr17Ni4Cu4Nb stainless steels during exposure in the marine atmosphere of Xisha islands for one year were studied.[Method]The corroded surface morphologies of unpassivated and passivated 0Cr17Ni4Cu4Nb stainless steels and the compositions of their corrosion products were examined by using scanning electron microscope(SEM),energy-dispersive spectrometer(EDS),video microscope(VM),and X-ray diffractometer(XRD).[Result]Corrosion occurred mainly in the form of pitting on the surface of 0Cr17Ni4Cu4Nb stainless steel after being exposed in marine atmosphere for a certain period no matter whether it was passivated or not.The relationship between weight loss and exposure time followed the power function.The corrosion product was mainly composed of β-FeOOH.Based on the comparison in the coverage of corrosion product and depth of corrosion pit,it was shown that passivation could improve the corrosion resistance of 0Cr17Ni4Cu4Nb stainless steel,but not provide a long-term protection in the marine atmosphere of Xisha islands.[Conclusion]It is necessary to explore a novel protection technology to improve the corrosion resistance of 0Cr17Ni4Cu4Nb stainless steel for its service in marine atmosphere.

martensitic precipitation hardening stainless steelpassivationmarine atmospherecorrosion behavior

杨丽媛、孙志华、詹中伟、刘明、赵明亮

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中国航发北京航空材料研究院,航空材料先进腐蚀与防护航空科技重点实验室,北京 100095

马氏体沉淀硬化不锈钢 钝化 海洋大气环境 腐蚀行为

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(3)
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