首页|适用于航空航天铝合金件的镀多层镍工艺

适用于航空航天铝合金件的镀多层镍工艺

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[目的]航空航天铝合金件镀镉工艺亟需找到环保的替代技术.[方法]制定了一种镀多层镍工艺,其工艺流程主要包括化学除油、超声波除油、碱腐蚀、出光、除垢、微腐蚀、第一次沉锌、退锌、第二次沉锌、化学预镀镍、镀半光亮镍、镀高硫镍、镀光亮镍、稀土电解保护和烘干.[结果]这种镀层在进行 168 h中性盐雾试验后无锈蚀,220 ℃热震试验中无起泡和脱落,在温度40 ℃和相对湿度93%的条件下进行的1 000 h恒定湿热试验后无可见变化.[结论]该工艺克服了单一化学镀镍层对铝合金基体无电化学保护作用的缺点,并以新开发的稀土电解保护工艺代替了传统的铬酸盐电解保护法,绿色环保,具有良好的应用前景.
Multilayer nickel plating process for aerospace aluminum alloy parts
[Introduction]The cadmium plating process of aerospace aluminum alloy parts urgently needs to find environmentally friendly alternative technologies.[Method]A multilayer nickel plating process was developed,including the following steps:chemical degreasing,ultrasound degreasing,alkaline etching,bright dipping,desmutting,slight etching,first zinc immersion,zinc stripping,secondary zinc immersion,electroless nickel pre-plating,semi-bright nickel plating,high-sulfur nickel plating,bright nickel plating,electrolytic passivation with rare earth,and drying.[Result]The coating obtained by the process endured 168 hours of neutral salt spray test without any corrosion product on its surface,did not blister or peel off during thermal shock test at 220 ℃,and remained unchanged in appearance after 1 000 hours of steady-state damp heat test at temperature 40 ℃ and relative humidity 93%.[Conclusion]This process overcomes the disadvantage that a single electrolessly plated nickel coating has no electrochemical protection effect on the aluminum alloy substrate,and replaces the traditional chromate electrolytic passivation method with a newly developed rare earth electrolytic passivation method,having environmental friendliness and good application prospect.

aluminum alloyelectroless nickel pre-platingmultilayer nickel platingelectrolytic passivation with rare earthadhesioncorrosion resistance

代朋民、郭崇武

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中航工业贵州华烽电器有限公司,贵州 贵阳 550006

广州超邦化工有限公司,广东 广州 510460

铝合金 化学预镀镍 多层镍电镀 稀土电解保护 结合力 耐蚀性

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(4)
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