首页|弹条渗锌涂层耐蚀性研究

弹条渗锌涂层耐蚀性研究

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[目的]研究弹条渗锌层、渗锌+硅酸盐封闭层及渗锌+油性漆封闭层在中性盐雾和二氧化硫环境下的耐蚀性.[方法]借助磁阻法测厚仪和金相显微镜筛选出不同厚度和形貌的渗锌层,然后分别进行硅酸盐封闭和油性漆封闭处理,采用扫描电镜和能谱仪分别观察封闭层分布情况和分析化学成分,最后进行中性盐雾和二氧化硫试验.[结果]硅酸盐封闭层以渗透于间隙的方式分布于渗锌层表层,较薄;油性漆封闭层以一种较为均匀且连续的方式覆盖于渗锌层表层之上,较厚.经120 h中性盐雾和二氧化硫试验后,渗锌层和渗锌+硅酸盐封闭层都有红锈生成,但后者的红锈程度较低,而渗锌+油性漆封闭层未出现红锈.[结论]渗锌层在增加硅酸盐封闭或油性漆封闭后,耐蚀性得到提升,虽然渗锌+油性漆封闭层的耐蚀效果最优,但应结合工艺、环保、安全、成本、产品使用条件等方面更为合理地选取防腐方式.
Corrosion resistance of zinc diffusion coating on clip
[Introduction] The corrosion resistance of clips treated by sherardizing, sherardizing + silicate sealing, and sherardizing + oil-based painting in neutral salt spray and sulfur dioxide environments is worth studying. [Method] The sherardizing layers with different thicknesses and morphologies were collected by using magnetoresistive thickness gauge and metallographic microscope, and then sealed with silicate and oil-based paint, respectively. The distribution and chemical composition of the sealing layers were examined by scanning electron microscopy and energy-dispersive spectroscopy. The neutral salt spray test and sulfur dioxide test were carried out. [Result] The silicate sealing layer, which was thin, was distributed on the surface of the sherardizing layer in the way of infiltration into the gaps. The oil-based painting layer, which was thick, was covered on the surface of the sherardizing layer in a more uniform and continuous way. After 120 hours of neutral salt spray test or sulfur dioxide test, red rust appeared on the unsealed and silicate-sealed sherardizing specimens, but the red rust area of the latter was less than that of the former. No red rust was formed on the sherardizing specimen sealed with oil-based paint. [Conclusion] The corrosion resistance of sherardizing layer can be improved by silicate sealing or oil-based painting as a post-treatment. Although the anticorrosion performance of oil-based painting is the best, the post treatment for sherardized products should be selected more reasonably in terms of operation, environmental friendliness, safety, cost, and service conditions.

clipspring steelsherardizingsealingsilicateoil-based paintcorrosion resistance

于毫勇、吕明奎

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铁科(天津)科技有限公司,天津 301700

弹条 弹簧钢 渗锌 封闭 硅酸盐 油性漆 耐蚀性

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(5)