电镀与涂饰2024,Vol.43Issue(7) :76-84.DOI:10.19289/j.1004-227x.2024.07.010

2205双相不锈钢在高温高压含H2S环境中的应力腐蚀开裂行为

Stress corrosion cracking behavior of 2205 duplex stainless steel in high-temperature,high-pressure,and H2S-containing environment

赵在鹏 蔡锐 陈家雄 吴镇江 何奇垚
电镀与涂饰2024,Vol.43Issue(7) :76-84.DOI:10.19289/j.1004-227x.2024.07.010

2205双相不锈钢在高温高压含H2S环境中的应力腐蚀开裂行为

Stress corrosion cracking behavior of 2205 duplex stainless steel in high-temperature,high-pressure,and H2S-containing environment

赵在鹏 1蔡锐 2陈家雄 1吴镇江 1何奇垚1
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作者信息

  • 1. 中国石油天然气集团有限公司超深层复杂油气藏勘探开发技术研发中心,新疆库尔勒 841000;新疆维吾尔自治区超深层复杂油气藏勘探开发工程研究中心,新疆库尔勒 841000;中国石油塔里木油田分公司,新疆库尔勒 841000
  • 2. 中国石油集团工程材料研究院有限公司,陕西西安 710077
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摘要

[目的]研究2205双相不锈钢油井管柱在含H2S、CO2气井实际服役工况环境下的应力腐蚀开裂行为和机理.[方法]通过模拟油气田现场工况环境,采用慢拉伸法和四点弯曲法在不同温度和H2S分压下进行了应力腐蚀开裂试验,按失重法测试了均匀腐蚀速率,并采用扫描电镜(SEM)和能谱仪(EDS)分析了腐蚀微观形貌和腐蚀产物.[结果]当H2S分压为0.10 MPa时,2205双相不锈钢处于应力腐蚀脆性断裂区,且在25℃时的应力腐蚀开裂敏感性最高.[结论]温度升高和加载应力能加快阳极溶解,令2205双相不锈钢的腐蚀速率增大.

Abstract

[Introduction]The stress corrosion cracking behavior and mechanism of 2205 duplex stainless steel production tubing in oil and gas well containing H2S and CO2 were studied.[Method]Under the simulated working environment of oil and gas field,stress corrosion cracking tests were conducted at different temperatures and H2S partial pressures by slow tensile method and four-point bending method. The general corrosion rate was calculated by weight loss method,and the corrosion micromorphology and corrosion products were analyzed by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS).[Result]When the H2S partial pressure was 0.10 MPa,2205 duplex stainless steel suffered from brittle fracture under stress corrosion condition,and its stress corrosion cracking sensitivity was highest at 25 ℃.[Conclusion]The increase of temperature and loading stress can accelerate the anodic dissolution rate,thereby the corrosion rate of 2205 duplex stainless steel increases.

关键词

双相不锈钢/应力腐蚀/硫化氢分压/阳极溶解

Key words

duplex stainless steel/stress corrosion/partial pressure of hydrogen sulfide/anodic dissolution

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基金项目

中国石油天然气集团有限公司科学研究与技术开发项目(2020B-4018)

出版年

2024
电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
参考文献量6
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