首页|HEDP浓度对烧结钕铁硼碱性无氰镀铜的影响

HEDP浓度对烧结钕铁硼碱性无氰镀铜的影响

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[目的]烧结钕铁硼(NdFeB)磁体在声电磁性器件中的应用日益广泛,但其耐蚀性较差,一般需要进行有效的表面处理以提高其耐腐蚀性能和使用寿命.[方法]采用以羟基乙叉二膦酸(HEDP)为主配位剂的碱性无氰体系对烧结 NdFeB磁体表面电镀铜.研究了HEDP质量浓度对Cu镀层外观、表面粗糙度、厚度、结合力和耐蚀性的影响.[结果]HEDP的质量浓度为100~150 g/L时所得Cu镀层表面较光亮,厚度约为1.55 μm,表面粗糙度较低,结合力和耐蚀性最佳.[结论]适宜的HEDP浓度有利于获得综合性能较好的Cu镀层.
Effect of HEDP concentration on alkaline cyanide-free copper electroplating of sintered NdFeB
[Introduction]Sintered neodymium-iron-boron(NdFeB)magnets are increasingly used in acousto-electromagnetic parts,it is necessary to conduct some effective surface treatments to improve their corrosion resistance and service lives.[Method]Copper electroplating was carried out on the surface of sintered NdFeB magnet in an alkaline cyanide-free bath with 1-hydroxyethylidene-1,1-diphosphonic acid(HEDP)as the main complexing agent.The effect of mass concentration of HEDP on the appearance,surface roughness,thickness,adhesion,and corrosion resistance of Cu coating was studied.[Result]The Cu coating electroplated with 100-150 g/L of HEDP was bright with a thickness of about 1.55 μm,low surface roughness,and the best adhesion and corrosion resistance.[Conclusion]Appropriate HEDP concentration in bath is favorable for forming a Cu coating with good comprehensive performance.

cyanide-free copper electroplatingsintered neodymium-iron-boron magnet1-hydroxyethylidene-1,1-diphosphonic acidadhesioncorrosion resistance

唐方宇、邵波、刘志恒、王春霞、史鑫

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西凡仪器(深圳)有限公司,广东 深圳 518000

南昌航空大学材料科学与工程学院,江西 南昌 330063

无氰镀铜 烧结钕铁硼磁体 羟基乙叉二膦酸 结合力 耐蚀性

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(10)