电镀与涂饰2024,Vol.43Issue(10) :17-22.DOI:10.19289/j.1004-227x.2024.10.003

HEDP浓度对烧结钕铁硼碱性无氰镀铜的影响

Effect of HEDP concentration on alkaline cyanide-free copper electroplating of sintered NdFeB

唐方宇 邵波 刘志恒 王春霞 史鑫
电镀与涂饰2024,Vol.43Issue(10) :17-22.DOI:10.19289/j.1004-227x.2024.10.003

HEDP浓度对烧结钕铁硼碱性无氰镀铜的影响

Effect of HEDP concentration on alkaline cyanide-free copper electroplating of sintered NdFeB

唐方宇 1邵波 1刘志恒 2王春霞 2史鑫2
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作者信息

  • 1. 西凡仪器(深圳)有限公司,广东 深圳 518000
  • 2. 南昌航空大学材料科学与工程学院,江西 南昌 330063
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摘要

[目的]烧结钕铁硼(NdFeB)磁体在声电磁性器件中的应用日益广泛,但其耐蚀性较差,一般需要进行有效的表面处理以提高其耐腐蚀性能和使用寿命.[方法]采用以羟基乙叉二膦酸(HEDP)为主配位剂的碱性无氰体系对烧结 NdFeB磁体表面电镀铜.研究了HEDP质量浓度对Cu镀层外观、表面粗糙度、厚度、结合力和耐蚀性的影响.[结果]HEDP的质量浓度为100~150 g/L时所得Cu镀层表面较光亮,厚度约为1.55 μm,表面粗糙度较低,结合力和耐蚀性最佳.[结论]适宜的HEDP浓度有利于获得综合性能较好的Cu镀层.

Abstract

[Introduction]Sintered neodymium-iron-boron(NdFeB)magnets are increasingly used in acousto-electromagnetic parts,it is necessary to conduct some effective surface treatments to improve their corrosion resistance and service lives.[Method]Copper electroplating was carried out on the surface of sintered NdFeB magnet in an alkaline cyanide-free bath with 1-hydroxyethylidene-1,1-diphosphonic acid(HEDP)as the main complexing agent.The effect of mass concentration of HEDP on the appearance,surface roughness,thickness,adhesion,and corrosion resistance of Cu coating was studied.[Result]The Cu coating electroplated with 100-150 g/L of HEDP was bright with a thickness of about 1.55 μm,low surface roughness,and the best adhesion and corrosion resistance.[Conclusion]Appropriate HEDP concentration in bath is favorable for forming a Cu coating with good comprehensive performance.

关键词

无氰镀铜/烧结钕铁硼磁体/羟基乙叉二膦酸/结合力/耐蚀性

Key words

cyanide-free copper electroplating/sintered neodymium-iron-boron magnet/1-hydroxyethylidene-1,1-diphosphonic acid/adhesion/corrosion resistance

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出版年

2024
电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
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