首页|中铝锌铝镁无铬自润滑产品的表面特性

中铝锌铝镁无铬自润滑产品的表面特性

Surface characteristics of chromium-free self-lubricating products for moderate-aluminum Al-Zn-Mg alloy coated steel sheet

扫码查看
[目的]中铝锌铝镁钢板亟需一款适合微电机使用场景的自润滑膜层.[方法]通过对中铝锌铝镁表面 3 种无铬自润滑产品的表面微观形貌及膜层成分进行探究,分析了不同表面处理方式的各项性能,并结合自润滑产品的组成特性及实际使用场景,考察了不同自润滑膜层的耐蚀性、耐磨性等关键性能,明晰了造成各项性能差异的原因.[结果]与 1#及 2#有机弱酸性体系无铬自润滑产品相比,3#有机-无机复合自润滑膜层是偏无机酸性体系,与钢板表面的界面反应更强,具有较好的附着力,耐蚀性、耐指纹性、导电性、耐磨性等性能也更优.[结论]3#无铬自润滑产品膜层中的磷酸根为腐蚀抑制剂,磷酸盐又是隔离层与粘结层的有效成分,可进一步提高膜层的抗腐蚀能力.氟钛酸作为该涂层的润滑添加剂,不仅充当了提高润滑涂层耐蚀性的缓蚀剂,还充当了填充剂,填充于膜层孔隙中,有利于致密自润滑膜的形成,有效地减小了摩擦因数,提高了成型性能.
[Introduction]A self-lubricating film suitable for micro-motor applications is urgently needed for Al-Zn-Mg alloy coated steel sheets.[Method]The properties of three types of chrome-free self-lubricating products for moderate-aluminum Al-Zn-Mg alloy coated steel sheets were studied by surface micromorphology observation and elemental composition analysis of the self-lubricating films.The key performances such as corrosion resistance and wear resistance of the self-lubricating films were examined,and the reasons of the differences in their performances were discussed in consideration of the compositional characteristics and actual applications of the self-lubricating products.[Result]As compared with 1#and 2#chrome-free weak organic acid self-lubricating products,3#organic-inorganic self-lubricating product is of inorganic acid,has stronger interfacial reaction with the steel surface,and produces a film with higher adhesion strength,corrosion resistance,fingerprint resistance,electrical conductivity,and wear resistance.[Conclusion]The 3#chrome-free self-lubricating product contains phosphate,which is not only a corrosion inhibitor,but also one of the effective components of the barrier layer and bonding layer,improving the corrosion resistance of the self-lubricating film.Fluorotitanic acid,as an additive,acts not only as a corrosion inhibitor to improve the corrosion resistance of the self-lubricating film,but also as a filler filling the pores in the film,which facilitates the formation of a compact self-lubricating film,effectively reduces the friction coefficient of the film,and improves the forming performance of Al-Zn-Mg alloy coated steel sheets.

zinc-aluminum-magnesium alloy coated steel sheetchromium-free self-lubricationorganic-inorganic compositeanticorrosionwear resistance

杨洋、郭宏南、陈倩

展开 >

宝钢湛江钢铁有限公司,广东 湛江 524072

锌铝镁钢板 无铬自润滑 有机-无机复合 防腐蚀 耐磨性

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(10)