首页|Q235碳钢在中性模拟土壤溶液中的缝隙腐蚀行为

Q235碳钢在中性模拟土壤溶液中的缝隙腐蚀行为

Crevice corrosion behavior of carbon steel in neutral simulated soil solution

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[目的]碳钢构件在中性土壤环境中的缝隙腐蚀行为值得探究.[方法]将Q235钢单一缝隙试样浸泡在模拟土壤溶液中,分析了腐蚀不同时间后试样的腐蚀速率、腐蚀形貌及腐蚀产物.[结果]Q235 钢在中性模拟土壤溶液中的腐蚀存在缝隙加速现象,初期在缝隙口发生明显的沿缝腐蚀,后期则在缝隙内发生点蚀.缝隙内外区域的主要腐蚀产物都是Fe3O4和FeOOH,且不受腐蚀时间影响.[结论]Q235钢在中性模拟土壤溶液中会发生明显的缝隙腐蚀,其腐蚀过程可分为初期均匀腐蚀、中期氧浓差电池引发缝隙腐蚀和后期闭塞电池自催化 3 个阶段.为确保碳钢结构在中性土壤环境中的服役安全性,需对钢结构的缝隙腐蚀采取必要的控制措施.
[Introduction]The crevice corrosion behavior of carbon steel components in neutral soil environment is worth studying.[Method]The Q235 carbon steel specimen with a single crevice was immersed in the simulated soil solution,and the corrosion rate,corrosion morphology,and corrosion products after different corrosion time were characterized.[Result]The corrosion of Q235 carbon steel was accelerated due to the existence of crevice in the neutral simulated soil solution.The crevice corrosion occurs significantly along the crevice opening at the initial stage,and then the pitting corrosion occurs inside the crevice.The corrosion products inside and outside the crevice were mainly Fe3O4 and FeOOH,and did not change with the extending of corrosion time.[Conclusion]Q235 carbon steel has obvious crevice corrosion in neutral simulated soil solution.The process of crevice corrosion can be divided into three stages:initial uniform corrosion,intermediate crevice corrosion induced by oxygen concentration cell,and later self-catalytic occluded cell corrosion.In order to ensure the safety of carbon steel structure serving in neutral soil environment,some measures should be taken to control the crevice corrosion.

carbon steelneutral simulated soil solutioncrevice corrosionproductmorphologymechanism

李莎莎、卢彩彬、曹雪雅、赵华宇、王鲲

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西北核技术研究所,陕西 西安 710024

碳钢 中性模拟土壤溶液 缝隙腐蚀 产物 形貌 机理

2024

电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
年,卷(期):2024.43(10)