电镀与涂饰2024,Vol.43Issue(10) :155-161.DOI:10.19289/j.1004-227x.2024.10.021

响应面法优化电化学-铁粉还原法处理高浓度硝酸盐电镀废水工艺

Response surface optimization of treatment process for high-nitrate-concentration electroplating wastewater by combining electrochemical technology with iron powder reduction

何潇
电镀与涂饰2024,Vol.43Issue(10) :155-161.DOI:10.19289/j.1004-227x.2024.10.021

响应面法优化电化学-铁粉还原法处理高浓度硝酸盐电镀废水工艺

Response surface optimization of treatment process for high-nitrate-concentration electroplating wastewater by combining electrochemical technology with iron powder reduction

何潇1
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作者信息

  • 1. 中化学南方建设投资有限公司,广东 广州 510080
  • 折叠

摘要

[目的]将电化学法和铁粉还原法相结合处理高浓度硝酸盐模拟电镀废水,通过响应面法优化处理工艺.[方法]采用中心复合法设计试验,研究了电压、初始pH、氯离子质量浓度和搅拌强度对硝酸盐去除效率的影响.[结果]在电压为13 V、初始pH为1、极间距为1.2 cm、氯离子质量浓度为3 000 mg/L、搅拌强度为450 r/min的条件下电解60 min后,硝酸盐和总氮的去除率分别达到84.04%和81.37%.[结论]采用电化学-铁粉还原法能够有效去除电镀废水中高浓度的硝酸盐.

Abstract

[Introduction]The process for treating a simulated high-nitrate-concentration electroplating wastewater by combining electrochemical technology with iron powder reduction was optimized by response surface method.[Method]The experiments were carried based on central composite design to study the effects of voltage,initial pH,mass concentration of chloride ions,and stirring rate on the removal efficiency of nitrate.[Result]After electrolysis under the conditions of voltage 13 V,initial pH 1,inter-electrode spacing 1.2 cm,mass concentration of chloride ions 3 000 mg/L,and stirring rate 450 r/min for 60 minutes,the removal rate was 84.04%for nitrate and 81.37%for total nitrogen.[Conclusion]The high concentration of nitrate can be effectively removed from the electroplating wastewater by combining electrochemical technology and iron powder reduction.

关键词

电镀废水/高浓度硝酸盐/电化学法/铁还原法/响应面法

Key words

electroplating wastewater/high nitrate concentration/electrochemical technology/iron reduction/response surface method

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出版年

2024
电镀与涂饰
广州市二轻工业科学技术研究所

电镀与涂饰

CSTPCD北大核心
影响因子:0.47
ISSN:1004-227X
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