首页|基于羟基含量抑制的环氧复合物外绝缘性能提升研究

基于羟基含量抑制的环氧复合物外绝缘性能提升研究

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无线传能复合绝缘子长期面临雨雾及污秽的恶劣环境挑战,其高效可靠的电能传输状态对环氧复合物的外绝缘能力提出了严苛要求.通过分子结构设计的方法改善环氧复合物憎水性能可以有效地提升其外绝缘性能,然而这种方法存在降低环氧复合物热学及机械性能的隐患.本研究采用特种双酚A改性环氧树脂作为改性剂,抑制了环氧复合物中羟基的含量,从而将环氧复合物的憎水性能及憎水迁移性能最大提升了 24.61%和 51.21%.改性环氧复合物断面粗糙度的增加阻碍了应力的传播,增强了其拉伸强度.环氧复合物表面水分的附着受到抑制,从而提升了环氧复合物在水珠及污秽条件下的外绝缘性能,经过 6h实验电压为 4.5 kV的耐漏电起痕实验后,环氧复合物表面蚀损深度最高下降了 86.18%,同时环氧复合物的污闪电压提升了 13.78%.对环氧复合物的热学及机械性能进行测试,特种改性剂的添加对其热稳定性及拉伸强度影响不大,本研究在不降低环氧复合物热学及机械性能的同时,有效改善了其外绝缘性能.本文研究结果可为无线传能复合绝缘子等外绝缘设备的绝缘材料设计方法提供一定参考.
Study on improving external insulation performance by inhibiting hydroxyl content of epoxy composites
Wireless power transmission insulators are long challenged by harsh environmental conditions such as rain,fog,and dirt,placing stringent demands on the external insulation capabilities of epoxy composites.Impro-ving the hydrophobic performance of epoxy composites through molecular structure modification can effectively en-hance their external insulation performance.However,this method has risks of reducing the thermal and mechani-cal performance of the epoxy composites.This study utilizes a special bisphenol A-modified epoxy resin as a modifi-er,suppressing the hydroxyl content in the epoxy composites,thereby improving their hydrophobicity and hydropho-bic migration performance.The surface water contact angle and hydrophobic migration of the epoxy composites in-creased by 24.61%,and 51.21%.The increase of the surface roughness of the modified epoxy composite hindered the propagation of stress and enhanced its tensile strength.The development of conductive water films on the surface of epoxy composites is inhibited,thus enhancing the external insulation performance of the epoxy composites under conditions of water droplets and dirt.After a 6h test at 4.5 kV for resistance to electrical tracking,the maximum depth of surface erosion on the epoxy composites decreased by 86.18%,and the pollution flashover voltage in-creased by 13.78%.The thermal and mechanical performance of the epoxy composites were tested,and the addi-tion of the special modifier had little impact on their thermal stability and tensile strength.This study effectively im-proved the external insulation performance of the epoxy composites without compromising their thermal and mechan-ical performance.The results of this study can provide a reference for the design of insulation materials for external insulation equipment such as composite insulators.

wireless power transmission insulatorsmolecular structure designwater repellencymigration of hy-drophobicityexternal insulation performance

王科、罗子民、彭晶、李会杰、尹芳辉

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云南电网有限责任公司电力科学研究院,云南 昆明 650217

清华大学深圳国际研究生院,广东 深圳 518055

无线传能复合绝缘子 分子结构设计 憎水性 憎水迁移性 外绝缘能力

南方电网科技项目

YNKJXM20222522

2024

电工电能新技术
中国科学院电工研究所

电工电能新技术

CSTPCD北大核心
影响因子:0.716
ISSN:1003-3076
年,卷(期):2024.43(8)
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