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电感耦合等离子体发射光谱法检测除盐水系统痕量阳离子

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提出了采用电感耦合等离子体发射光谱仪(ICP-AES)测量除盐水中Ca、Mg、Al的方法,对分析条件进行优化,并对上述离子的方法检出限、准确度、回收率进行测定与评估.结果表明:ICP-AES法可快速、准确、稳定地测量除盐水中Ca、Mg、Al,其中各离子的方法检出限为Ca 0.5 μg/L、Mg 0.5 μg/L、Al 2 μg/L,各离子的加标回收率在 98%~102%,相对标准偏差均小于 1.5%.所提方法弥补了 3~6 号机组除盐水制水系统新增 Ca、Mg、Al等阳离子没有专门分析方法的不足,实现了一次进样同时检测多种离子,提高了对田湾核电站二期除盐水系统水质的检测能力,对后续除盐水系统调试、运行期间水质的分析具有重要意义.
Detecting Trace Cations in Desalinated Water by Inductively Coupled Plasma Emission Spectroscopy
In this paper,the method of measuring Ca,Mg and Al in saline water(ICP-AES)was studied,the analysis conditions were optimized,and detection limit,accuracy and recovery rate of the above ions were determined and evalua-ted.The results show that ICP-AES method can quickly,accurately and stably measure Ca,Mg and Al in desalinated wa-ter,and the detection limits of the ions are:Ca 0.5 μg/L,Mg 0.5 μg/L,Al 2 μg/L,with spike recovery of each ion of 98%~102%and relative standard deviation lower than 1.5%.The method provides feasible way to measure new cations of the water desalination and preparation system of unit 3~6 of Tianwan nuclear power plant,such as Ca,Mg,Al,im-proves the detection capability of water quality,and has great significance for subsequent brine system debugging and in-operation water quality analysis.

desalinated waterICP-AEScationrecoverydetection limitmulti-channel

陈勇

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江苏核电有限公司,江苏 连云港 222000

除盐水 ICP-AES 阳离子 回收率 方法检出限 多通道

2024

电工技术
重庆西南信息有限公司(原科技部西南信息中心)

电工技术

影响因子:0.177
ISSN:1002-1388
年,卷(期):2024.(3)
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