东昆仑造山带海德乌拉铀矿床成矿流体特征研究
Study on fluid characteristics of the Haidewula uranium deposit,East Kunlun orogenic belt
朱坤贺 1王凯兴 1刘晓东 2段建华 3李彦强 3吴佳 1余驰达 2雷勇亮1
作者信息
- 1. 核资源与环境国家重点实验室,东华理工大学,江西南昌,330013;东华理工大学地球科学学院,江西南昌,330013
- 2. 核资源与环境国家重点实验室,东华理工大学,江西南昌,330013
- 3. 青海省核工业地质局,青海西宁,810001
- 折叠
摘要
东昆仑造山带海德乌拉铀矿床是近些年西北地区最新探明的与火山岩有关的独立铀矿床,该矿床的发现为东昆仑造山带探寻热液型铀矿床提供了指示意义.本文选择与海德乌拉铀矿成矿期相关的透明矿物(粉红色方解石、紫黑色萤石及石英)作为研究对象,系统地开展C-H-O同位素和流体包裹体研究,查明该矿床成矿流体的来源与性质,并探讨矿床成因.研究结果表明,海德乌拉铀矿床成矿期石英中主要为H2O气液两相包裹体,少见CO2-H2O两相包裹体;在粉红色方解石脉、紫黑色萤石脉中流体包裹体均含H2O气液两相包裹体,在粉红色方解石脉中偶见纯液相包裹体,均未见到纯气相及含固相包裹体.成矿期粉红色方解石、紫黑色萤石及石英中包裹体均一温度范围分别为133～187℃(均值163℃)、127～204℃(均值169℃)、183～287℃(均值219℃),盐度范围分别为 1.40％～7.02％NaCleq(均值 3.65％NaCleq)、0.53％～3.06％NaCleq(均值 1.26％NaCleq)、7.17％～17.26％NaCleq(均值为11.46％NaCleq).流体包裹体气相成分以H2O为主,另含少量CO2等.C-H-O同位素实验数据表明,流体中δ13CFl uid-V-PDB、δDFluid-V-SMOW、δ18 O Fluid-V-SMOW 值的变化范围分别为-1.59‰～-1.00‰、-71‰～-63‰、0.03‰～3.72‰,表明成矿流体并非单一来源,可能为大气降水与岩浆水混合来源.此外,沥青铀矿的沉淀主要是由于流体与围岩的相互反应所引起的物理化学条件变化加上流体沸腾/CO2去气,最终导致了沥青铀矿等成矿物质发生大规模的卸载与沉淀.
Abstract
The Haidewula uranium deposit in the East Kunlun orogenic belt is a newly discovered independent uranium deposit related to volcanic rocks in Northwest China.The discovery of the deposit provides an indication for the exploration of hydrothermal uranium deposits in the East Kunlun orogenic belt.in this paper,the transparent minerals(pink calcite,purple black fluorite and quartz)related to the ore-forming period of the deposit are selected as the research objects.A systematic study of the C-H-O isotopes and fluid inclusions are carried out to find out the source and nature of the ore-forming fluid,and to explore the genesis of the deposit.The results show that the quartz of the ore forming period of the Haidewula uranium deposit is mainly composed of H2O gas-liquid two-phase inclusions,with few CO2-H2O two-phase inclusions;fluid inclusions in calcite vein and fluorite vein contain H2O gas-liquid two-phase inclusions.Pure liquid phase inclusions are occasionally seen,but pure gas phase and solid phase inclusions are not seen in calcite veins.The homogenization temperature range of inclusions in calcite,fluorite and quartz during mineralization is from 133℃ to 187℃(mean 163℃),from 127℃ to 204℃(mean 169℃),and from 183℃ to 287℃(mean 219℃)respectively,and the salinity range is from 1.40％NaCleq to 7.02％NaCleq(mean 3.65％NaCleq),from 0.53％NaCleq to 3.06％NaCleq(mean 1.26％NaCleq),from 7.17％NaCleq to 17.26％NaCleq(mean 11.46％NaCleq).The gas phase composition of fluid inclusions is mainly H2O,and a small amount of CO2.The experimental data of C-H-O isotope show that the variation ranges of δ13 CFluid-V-PDB,δDFluid-V-SMOW,δ18 OFluid-v-smow values are from-1.59‰ to-1.00‰,from-71 ‰ to-63‰,from 0.03‰ to 3.72‰ respectively,indicating that the ore-forming fluid is not a single source,and may be a mixed source of atmospheric precipitation and magmatic water.In addition,the precipitation of pitchblende is mainly due to the changes in physical and chemical conditions caused by the interaction between fluid and hosted-rock,as well as fluid boiling/CO2 degassing,leading to large-scale unloading and precipitation of the pitchblende and other uranium minerals.
关键词
火山岩型铀矿床/成矿流体/流体包裹体/激光拉曼光谱/C-H-O同位素Key words
volcanic-hosted uranium deposit/ore-forming fluid/fluid inclusion/laser Raman spectroscopy/C-H-O isotopes引用本文复制引用
基金项目
国家自然科学基金项目(42072095)
中国核工业集团高校科研攻关项目(201619)
教育厅科技计划项目(GJJ200717)
青海省科技厅重点研发与转化计划(2021-SF-157)
东华理工大学研究生创新基金项目(DHYC-202212)
出版年
2024
国家科技期刊平台
NSTL
万方数据