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我国燃煤工业锅炉碳排放强度分布及影响因素研究

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锅炉是能源消费大户和主要的大气污染物及碳排放源,准确量化锅炉碳排放是摸清我国碳排放"家底"的基础。结合能效测试与碳氧化率计算,提出了基于燃料转化与烟气CO2排放测试相结合的碳排放量化方法,进一步引入热负荷,建立了碳排放强度计算方法。基于615台燃煤工业锅炉实炉测试数据样本,对锅炉碳排放强度计算方法进行验证,同时分析了燃煤工业锅炉碳排放强度总体分布情况,燃煤工业锅炉的碳排放强度绝大部分分布在80~140 kgCO2/GJ之间,最大值为137。4 kgCO2/GJ,最小值为82。5 kgCO2/GJ,平均值为110。8 kgCO2/GJ。进一步分析了单位热值含碳量、碳氧化率、热效率、容量及负荷等因素对锅炉碳排放强度分布的影响。分析结果表明,锅炉碳排放强度受单位热值含碳量影响较大,呈现明显的正相关性,无烟煤相较烟煤和褐煤有较高的碳排放强度,锅炉热效率升高时,碳排放强度基本呈下降趋势,以1台40 t/h层燃炉为例进行了敏感性分析,排烟温度、排烟含氧量和进风温度对碳排放强度的影响较大,炉渣含碳量、飞灰含碳量的影响较小;排烟温度增加10℃,碳排放强度增大0。59 kgCO2/GJ,排烟含氧量增加1%,碳排放强度增大0。50 kgCO2/GJ。
Study on the distribution of carbon emission intensity from coal-fired industrial boilers in China and its influencing factors
The boiler is a major energy consumer and an important source of atmospheric pollutants and carbon emissions in China.Accurately quantifying carbon emissions from boilers is the basis for understanding the overall carbon footprint of the country.A method for carbon emission quantification that combines energy efficiency testing with carbon oxidation rate calculations and flue gas CO2 emission tests were proposed.Furthermore,it introduced heat load to establish a methodology for calculating carbon emission intensity.The proposed carbon emission intensity calculation method was validated based on a dataset of 615 real-world tests conducted on coal-fired industrial boilers.The study also analyzed the overall distribution pattern of carbon emission intensity among these boilers.The majority of coal-fired industrial boilers had a carbon emission intensity ranging between 80~140 kgCO2/GJ,with the maximum value recorded at 137.4 kgCO2/GJ and the minimum at 82.5 kgCO2/GJ,while the average stands at 110.8 kgCO2/GJ.The research further delves into the impact of factors such as carbon content per unit of heat value,carbon oxidation rate,thermal efficiency,boiler capacity,and operating load on the distribution of carbon emission intensity.The results indicated that the carbon emission intensity of boilers was significantly influenced by the carbon content per unit calorific value,exhibiting a distinct positive correlation.Anthracite exhibited a higher carbon emission intensity compared to bituminous coal and lignite.As boiler thermal efficiency increased,the carbon emission intensity generally showed a downward trend.Taking a layer-combustion boiler with the capacity of 40t/h as an example,sensitivity analysis was conducted.The influence of the exhaust flue gas temperature,oxygen content in flue gas and inlet air temperature on the carbon emission intensity is significant,while the influence of carbon content in slag and fly ash is relatively small.When the exhaust flue gas temperature increases by 10℃,the carbon emission intensity rises by 0.59 kgCO2/GJ.Upon an increase of 1%in the oxygen content in flue gas,the carbon emission intensity increases by 0.50 kgCO2/GJ.

coal-fired industrial boilerscarbon emissionsquantificationcarbon emission intensitycarbon oxidation rate

刘雪敏、胡浩南、刘超、肖显斌、笪耀东

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低碳热力发电技术与装备全国重点实验室,国家市场监管技术创新中心(锅炉清洁低碳高效燃烧与安全评价),中国特种设备检测研究院,北京 100029

华北电力大学新能源学院,北京 102206

怀柔实验室山西研究院,山西 太原 030032

燃煤工业锅炉 碳排放 单位热值含碳量 碳排放强度 碳氧化率

2024

电力科技与环保
国电科学技术研究院

电力科技与环保

影响因子:0.653
ISSN:1674-8069
年,卷(期):2024.40(6)