首页|钨酸铋-石墨烯复合光催化剂的制备及其光催化性能

钨酸铋-石墨烯复合光催化剂的制备及其光催化性能

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利用溶剂热法,在N,N-二甲基甲酰胺与乙二醇混合溶剂中制备了钨酸铋-石墨烯光催化剂.通过XRD、SEM、TEM、EDS和DRS对纯相钨酸铋及钨酸铋-石墨烯催化剂的形貌及性能进行表征,证明钨酸铋成功复合在石墨烯上,且钨酸铋-石墨烯催化剂的光谱吸收延伸至可见光.在可见光下,纯相钨酸铋及钨酸铋-石墨烯分别对罗丹明B(RhB)进行降解,结果表明,钨酸铋-石墨烯与纯相钨酸铋相比,前者表现出更好的光催化性能,与光生电子与空穴能够快速分离有关.相同时间(40 min)与光照条件下,当钨酸铋复合质量分数为0.6% 的石墨烯时,对污染物RhB的降解率可达84.0%,而纯相钨酸铋的降解率仅为67.2%.
Preparation and properties of Bi2WO6-RGO composite photo-catalysts
Bi2WO6-RGO photocatalyst was prepared by solvothermal method in the mixed solvents of N,N-dimethylformamide and ethylene glycol.The structure,physical and chemical properties of pure Bi2WO6and Bi2WO6-RGO composite catalysts were characterized by XRD,SEM,TEM,EDS and DRS.The results showed that Bi2WO6-RGO was successfully composited with grapheme.UV-vis spectra showed that Bi2WO6-RGO photocatalysts had strong adsorption in the visible light region. The rhodamine B(RhB)pollutant was degraded by Bi2WO6or Bi2WO6-RGO catalysts under visible light.The results confirmed that Bi2WO6-RGO exhibited better photocatalytic activity than pure Bi2WO6,which was attributed to accelerated separation of photo electron from holes in the composite catalyst.At the same time(40 min)and light conditions,the degradation rate of pollutant(RhB)by Bi2WO6-RGO(0.6%)was high up to 84.0%,while its degradation rate by the pure Bi2WO6was only 67.2%.

photocatalystgraphenesolvothermal methodBi2WO6

姜宇晴、张新欣、兰梦、薛芒、董晓丽

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大连工业大学 轻工与化学工程学院,辽宁 大连 116034

光催化剂 石墨烯 溶剂热法 钨酸铋

国家自然科学基金

21476033

2018

大连工业大学学报
大连工业大学

大连工业大学学报

CSTPCD北大核心
影响因子:0.295
ISSN:1674-1404
年,卷(期):2018.37(2)
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