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铝掺杂钛酸锶光催化剂的制备及光催化性能

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采用溶胶-凝胶法以氯化锶为锶源、钛酸四丁酯为钛源制备了不同铝掺杂量的钙钛矿型SrTiO3,利用X射线衍射、紫外-可见漫反射光谱、扫描电镜、X射线能谱等对催化剂的理化性质和光催化性能进行了研究。制备的SrTiO3(Al-0。3)样品为钙钛矿型,铝元素被成功掺杂,铝元素的掺杂使原催化剂粒径变小、禁带宽度变窄、光生电子与空穴的复合率降低。铝改性提高了 SrTiO3光催化性能,SrTiO3(Al-0。3)可在6 h内将苯酚降解96。0%以上。重复利用实验表明,铝改性SrTiO3具有较好的稳定性。
Preparation and photocatalytic performance of aluminum-doped strontium titanate photocatalysts
Perovskite-type SrTiO3 with different amounts of dopant aluminum(Al)was prepared by sol-gel method using strontium chloride as strontium source and tetrabutyl titanate as titanium source.The physicochemical and photocatalytic properties of the catalysts were studied by X ray diffraction,UV-Vis diffuse reflection spectrum,scanning electron microscopy and energy-dispersive X ray spectroscopy.The as-prepared SrTiO3(Al-0.3)sample is perovskite type,and aluminum was successfully doped.The doping of aluminum decreased the particle size of the pristine catalysts,narrowed the band gap,and reduced the recombination rate of photogenerated electrons and holes.The photocatalytic performance of SrTiO3(Al-0.3)was improved by aluminum modification.The photocatalytic degradation efficiency of phenol by SrTiO3(Al-0.3)can reach more than 96.0%within 6 h.The cycling experiments showed that aluminum modified-SrTiO3 had good stability.

photocatalysisstrontium titanatealuminum dopingphenol

张超、张秀芳、王冠龙

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大连工业大学 轻工与化学工程学院,辽宁 大连 116034

光催化 钛酸锶 铝掺杂 苯酚

国家自然科学基金

21906013

2024

大连工业大学学报
大连工业大学

大连工业大学学报

影响因子:0.295
ISSN:1674-1404
年,卷(期):2024.43(3)