大连工业大学学报2024,Vol.43Issue(3) :183-188.DOI:10.19670/j.cnki.dlgydxxb.2023.6010

海藻酸钠/单宁酸-铁复合物近红外光热响应纤维的制备及表征

Preparation and characterization of sodium alginate/tannic acid-ironcomposites fiber with near-infrared photo-thermal responsive behavior

王鹏祥 于跃 房少康 李慧荣 冯世达 张森 王艳
大连工业大学学报2024,Vol.43Issue(3) :183-188.DOI:10.19670/j.cnki.dlgydxxb.2023.6010

海藻酸钠/单宁酸-铁复合物近红外光热响应纤维的制备及表征

Preparation and characterization of sodium alginate/tannic acid-ironcomposites fiber with near-infrared photo-thermal responsive behavior

王鹏祥 1于跃 1房少康 1李慧荣 1冯世达 1张森 1王艳1
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作者信息

  • 1. 大连工业大学纺织与材料工程学院,辽宁 大连 116034
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摘要

以简易方法制备的单宁酸-铁复合物(TA-Fe3+)与海藻酸钠(SA)共混,通过湿法纺丝制备了具有近红外光热响应性的SA/TA-Fe3+复合纤维.研究了 TA-Fe3+复合物含量对SA/TA-Fe3+纺丝液流变性能和SA/TA-Fe3+复合纤维力学及光热性能的影响,借助单纤维强力机、红外光谱仪、扫描电镜、红外热成像仪对SA/TA-Fe3+复合纤维的性能进行了表征.研究表明,TA-Fe3+复合物含量对纺丝液黏度几乎没有影响,复合纤维断裂强度都大于2.1 cN/dtex;随着TA-Fe3+复合物含量的增加,复合纤维的近红外光热响应更加敏感.通过调节TA-Fe3+复合物添加量可以满足近红外光热响应复合纤维不同升温要求应用的需求.

Abstract

The SA/TA-Fe3+fiber with near-infrared photo-thermal responsive behavior was prepared by wet spinning of the blending solutions of tannic acid-iron composites and sodium alginate(SA).The effects of molar ratios of FeCl3 to TA on the rheological properties of SA/TA-Fe3+spinning solution and the mechanical and photo-thermal responsive behaviors of SA/TA-Fe3+fiber were studied.The properties of SA/TA-Fe3+fibers were characterized by single fiber strength machine,FT-IR,scanning electron microscopy and infrared thermal imaging analysis.The results showed that the content of TA-Fe3+composites scarcely changed the viscosity of the spinning solution.The breaking strength of SA/TA-Fe3+fibers was above 2.1 cN/dtex.With the increase of TA-Fe3+content,the near-infrared photo-thermal responsive behavior of the composite fiber was more sensitive.The requirements of elevating the temperature of SA/TA-Fe3+fiber for different applications could be satisfied by adjusting the addition of TA-Fe3+composites.

关键词

光热材料/海藻酸钠/单宁酸-铁/近红外光热响应

Key words

photothermal materials/sodium alginate/tannic acid-iron/near infrared photothermal response

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基金项目

辽宁省教育厅科研项目(J2020103)

出版年

2024
大连工业大学学报
大连工业大学

大连工业大学学报

影响因子:0.295
ISSN:1674-1404
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