大连工业大学学报2024,Vol.43Issue(5) :325-329.DOI:10.19670/j.cnki.dlgydxxb.2023.6012

改性TiO2/CMCS/SA杂化纤维的光催化自清洁性能

Photocatalytic self-cleaning performance of modified TiO2/CMCS/SA hybrid fibers

孙胜南 程晨 暴达 贾尚印 周永春 张森
大连工业大学学报2024,Vol.43Issue(5) :325-329.DOI:10.19670/j.cnki.dlgydxxb.2023.6012

改性TiO2/CMCS/SA杂化纤维的光催化自清洁性能

Photocatalytic self-cleaning performance of modified TiO2/CMCS/SA hybrid fibers

孙胜南 1程晨 1暴达 1贾尚印 1周永春 1张森1
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作者信息

  • 1. 大连工业大学 纺织与材料工程学院,辽宁 大连 116034
  • 折叠

摘要

将壳聚糖(CS)包覆在二氧化钛(TiO2)表面上制备了改性TiO2核壳粒子,并利用湿法纺丝技术将核壳粒子引入羧甲基壳聚糖(CMCS)/海藻酸钠(SA)杂化纤维中,制备了具有自清洁功能的纺织材料.紫外-可见分光光度计、扫描电子显微镜、红外光谱仪和单纤强力仪对杂化纤维表征结果表明,引入核壳粒子的改性TiO2/CMCS/SA杂化纤维具有较好的光催化性能和力学性能;当核壳粒子在杂化纤维中的质量分数为0.3%时,改性TiO2/CMCS/SA杂化纤维的断裂强度最高达到3.56 cN/dtex,光催化效率达到80%;与CMCS/SA杂化纤维相比,断裂强度提高了 16.34%,光催化效率提高了 20%.

Abstract

The modified titanium dioxide(TiO2)particles with core-shell shape were prepared by coating chitosan(CS)on the surface of TiO2,and a type of textile material with self-cleaning performance was prepared by introducing core-shell particles into carboxymethyl chitosan(CMCS)/sodium alginate(SA)hybrid fiber through wet spinning method.The hybrid fibers were characterized by UV-Vis spectrophotometer,scanning electron microscope,infrared spectrometer and single fiber strength meter.The results showed that the modified TiO2/CMCS/SA hybrid fibers exhibited excellent photo-catalytic and mechanical properties after introduction of core-shell particles.When the content of core-shell particles in the hybrid fibers was 0.3%,the fracture strength of the modified TiO2/CMCS/SA hybrid fibers was highest to 3.56 cN/dtex and their photo-catalytic efficiency was up to 80%.Compared with CMCS/SA hybrid fibers,the fracture strength and photo-catalytic efficiency was increased by 16.34%and 20%,respectively.

关键词

二氧化钛/核壳粒子/湿法纺丝/海藻酸钠/自清洁

Key words

titanium dioxide/core-shell particles/wet spinning/sodium alginate/self-cleaning

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基金项目

辽宁省教育厅科学研究经费项目(J2020047)

出版年

2024
大连工业大学学报
大连工业大学

大连工业大学学报

影响因子:0.295
ISSN:1674-1404
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