首页|改性TiO2/CMCS/SA杂化纤维的光催化自清洁性能

改性TiO2/CMCS/SA杂化纤维的光催化自清洁性能

扫码查看
将壳聚糖(CS)包覆在二氧化钛(TiO2)表面上制备了改性TiO2核壳粒子,并利用湿法纺丝技术将核壳粒子引入羧甲基壳聚糖(CMCS)/海藻酸钠(SA)杂化纤维中,制备了具有自清洁功能的纺织材料.紫外-可见分光光度计、扫描电子显微镜、红外光谱仪和单纤强力仪对杂化纤维表征结果表明,引入核壳粒子的改性TiO2/CMCS/SA杂化纤维具有较好的光催化性能和力学性能;当核壳粒子在杂化纤维中的质量分数为0.3%时,改性TiO2/CMCS/SA杂化纤维的断裂强度最高达到3.56 cN/dtex,光催化效率达到80%;与CMCS/SA杂化纤维相比,断裂强度提高了 16.34%,光催化效率提高了 20%.
Photocatalytic self-cleaning performance of modified TiO2/CMCS/SA hybrid fibers
The modified titanium dioxide(TiO2)particles with core-shell shape were prepared by coating chitosan(CS)on the surface of TiO2,and a type of textile material with self-cleaning performance was prepared by introducing core-shell particles into carboxymethyl chitosan(CMCS)/sodium alginate(SA)hybrid fiber through wet spinning method.The hybrid fibers were characterized by UV-Vis spectrophotometer,scanning electron microscope,infrared spectrometer and single fiber strength meter.The results showed that the modified TiO2/CMCS/SA hybrid fibers exhibited excellent photo-catalytic and mechanical properties after introduction of core-shell particles.When the content of core-shell particles in the hybrid fibers was 0.3%,the fracture strength of the modified TiO2/CMCS/SA hybrid fibers was highest to 3.56 cN/dtex and their photo-catalytic efficiency was up to 80%.Compared with CMCS/SA hybrid fibers,the fracture strength and photo-catalytic efficiency was increased by 16.34%and 20%,respectively.

titanium dioxidecore-shell particleswet spinningsodium alginateself-cleaning

孙胜南、程晨、暴达、贾尚印、周永春、张森

展开 >

大连工业大学 纺织与材料工程学院,辽宁 大连 116034

二氧化钛 核壳粒子 湿法纺丝 海藻酸钠 自清洁

辽宁省教育厅科学研究经费项目

J2020047

2024

大连工业大学学报
大连工业大学

大连工业大学学报

影响因子:0.295
ISSN:1674-1404
年,卷(期):2024.43(5)