首页|支座用石墨烯/导电炭黑橡胶材料的制备与性能

支座用石墨烯/导电炭黑橡胶材料的制备与性能

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以石墨烯和特制导电炭黑为功能填料,溴化丁基橡胶(BIIR)为基胶,制备出阻尼性能较好的导电橡胶材料。针对石墨烯/导电炭黑10种不同的组分,开展了力学性能、动态力学性能与电阻率测试实验,探究了加入石墨烯与导电炭黑对BIIR性能的影响规律。结果表明,导电炭黑对BIIR材料有补强效果,石墨烯/导电炭黑协同并用可以有效提高BIIR的阻尼性能与导电性能。在每100 g总胶料中添加40 g导电炭黑时,BIIR/导电炭黑复合材料的拉伸强度与撕裂强度分别达到20。28 MPa和45。66 kN/m。当导电炭黑和石墨烯并用组分的质量比为40∶10时,BIIR/导电炭黑/石墨烯复合橡胶材料最大损耗因子提升至0。5,电阻率为3 646 Ω·cm。复合材料的导电炭黑和石墨烯组分最优质量比为40∶5。制备得到的新型复合材料具有较好的力学性能、阻尼性能与导电性能,可为隔震支座用高阻尼导电橡胶的制备提供参考。
Preparation and performance of graphene/conductive carbon black compounded rubber material for bearings
The conductive rubber materials with better damping performance were prepared by using graphene/conductive carbon black(CCB)as functional fillers and brominated butyl rubber(BIIR)as base rubber.The mechanical properties,dynamic mechanical properties(DMA)and resistivity test experiments of 10 formula-tions with different graphene/CCB components were performed to investigate the influence law of adding gra-phene and CCB on the performance of BIIR.The results show that CCB has a reinforcing effect on the BIIR material,and the synergistic use of graphene/CCB can effectively improve the damping and conductive prop-erties of BIIR.The tensile and tear strength of BIIR/CCB composites reach 20.28 MPa and 45.66 kN/m when 40 g CCB is added to every 100 g total rubber.The maximum loss tangent of the BIIR/CCB/graphene composite rubber material is increased to 0.5 with a resistivity of 3 646 Ω·cm when the mass ratio of CCB to grapheme composition is 40∶10.The optimal ratio of CCB to graphene components for the composites is 40∶5.The prepared new composite material has good mechanical properties,damping properties and electrical con-ductivity.The results can provide a reference for the preparation of high damping conductive rubber bearings.

bromobutyl rubbergrapheneconductive carbon blackconductive rubberbearings

吴宜峰、张啸天、王浩、李爱群、张瑞君、张恒源、刘跃庭

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北京建筑大学土木与交通工程学院,北京 102600

东南大学土木工程学院,南京 211189

衡水震泰隔震器材有限公司,衡水 053000

溴化丁基橡胶 石墨烯 导电炭黑 导电橡胶 隔震支座

国家自然科学基金资助项目北京市教育委员会科研计划资助项目北京建筑大学研究生创新资助项目

51908024KM202310016012PG2023039

2024

东南大学学报(自然科学版)
东南大学

东南大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.989
ISSN:1001-0505
年,卷(期):2024.54(1)
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