首页|仿生水泥气凝胶的设计制备与性能分析

仿生水泥气凝胶的设计制备与性能分析

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针对传统建筑材料高力学性能和高隔热性能难以平衡的矛盾,受到深海墨鱼层-壁结构的启发,通过可控的定向冷冻法诱导水泥水化产物在聚合物溶液中成核形成仿生微结构,制备工艺选择灵活低能耗的冷冻干燥技术,设计并创造定向多孔的新型水泥气凝胶.结果表明,这种水泥气凝胶密度低至15.02 kg/m3,孔隙率高达90.64%,导热系数低至0.020 W/(m·K),同时具有-0.168的负泊松比,高达1 216.88 MPa/(cm-3·g)的比强度等优异的综合性能.在70%应变条件下,钙硅质量比为1.0时,所制备的水泥气凝胶抗压强度达到最大值,为33.89 MPa.此外,水泥气凝胶内部具有曲折的多孔结构,这使其具有良好的吸声性能,噪声衰减系数可达0.8.
Design and fabrication of bioinspired cement aerogel and its performance analysis
To address the contradiction of achieving a balance between high mechanical performance and high thermal insulation in traditional building materials,inspiration was drawn from the"layer-wall"structure of the deep-sea cuttlefish.By utilizing a controlled directional freezing method,calcium silicate hydrate nucleated and formed a biomimetic microstructure within a polymer solution.The manufacturing process adopted a ver-satile and low-energy-consuming freeze-drying technique,to design and create a novel,directionally porous cement aerogel.The results indicate that this cement aerogel has an exceptionally low density of 15.02 kg/m3,a porosity of up to 90.64%,and a thermal conductivity as low as 0.020 W/(m·K).Additionally,it exhibits a negative Poisson's ratio of-0.168 and a high specific strength of 1 216.88 MPa/(cm-3·g).Under 70%strain,the cement aerogel prepared with a calcium to silicon mass ratio of 1.0 exhibites its maximum compres-sive strength of 33.89 MPa.Moreover,the intricate porous structure of the cement aerogel provides excellent sound absorption properties,with a noise attenuation coefficient of up to 0.8.

cement aerogelthermal insulationlightweightstrengthsound absorption

杜丰音、佘伟

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东南大学材料科学与工程学院,南京 211189

东南大学江苏省土木工程材料重点实验室,南京 211189

水泥气凝胶 隔热 轻质 高强 吸声

国家自然科学基金面上项目

52278247

2024

东南大学学报(自然科学版)
东南大学

东南大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.989
ISSN:1001-0505
年,卷(期):2024.54(2)
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