首页|基于Aspen Plus的煤部分气化氢电联产系统模拟

基于Aspen Plus的煤部分气化氢电联产系统模拟

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为了提高煤制氢系统的能源利用效率,减少碳排放,构建了4种以煤部分气化为基础的新型氢电联产系统.基于Aspen Plus软件,采用系统效率、制氢效率作为评价标准,对各系统进行模拟与对比分析.结果表明:存在不同氧煤比与碳转化率使得系统效率达到最高,系统1~4分别在碳转化率为60%、85%、65%、60%时达到最高系统效率;各系统效率与气化效率随着气化温度的提高,呈先迅速增长后趋于平稳趋势;各系统效率与气化效率随着气化压力的提高,呈先迅速减少后趋于平稳趋势;在氧煤比为0.33,气化压力为2 MPa,气化温度为1 000 ℃工况下系统1~4效率分别为59.12%、66.13%、62.21%和58.57%;采用CO2与O2作为气化剂,且CO2与O2的质量比为4∶1的煤部分气化加压富氧燃烧循环系统(系统2)在各项标准下具有优势,为最佳氢电联产系统.
Simulation of hydrogen-electricity co-production system of coal partial gasification based on Aspen Plus
To improve the energy efficiency of coal-based hydrogen production and reduce carbon emissions,four new hydrogen-electricity cogeneration systems based on coal partial gasification were constructed.The sys-tem efficiency and hydrogen production efficiency were used as evaluation criteria to simulate and compare the systems using Aspen Plus.The results show that there are different oxygen-coal ratios and carbon conversion rates to achieve the highest system efficiency.System 1 to 4 reach the highest system efficiency when the car-bon conversion rate is 60%,85%,65%,and 60%,respectively.With the increase of gasification tempera-ture,the efficiency and gasification efficiency of each system first increase rapidly and then tend to be stable.With the increase of gasification pressure,the efficiency and gasification efficiency of each system first de-crease rapidly and then tend to be stable.When the oxygen-coal ratio is 0.33,the gasification pressure is 2 MPa,and the gasification temperature is 1 000 ℃,the efficiency of system 1 to 4 is 59.12%,66.13%,62.21%and 58.57%,respectively.The coal partial gasification pressurized oxygen-enriched combustion cy-cle system(System 2),which uses CO2 and O2 as gasification agents,and with a mass ratio of CO2 to O2of 4∶1,has advantages under various standards and is the best hydrogen-electricity cogeneration system.

coal partial gasificationsemi-coke pressurized oxygen-rich combustionsystem modelingther-modynamic analysis

张泽祎、李照志、邵应娟、钟文琪

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东南大学能源热转换及其过程测控教育部重点实验室,南京 210096

煤炭部分气化 半焦加压富氧燃烧 系统建模 热力学分析

国家自然科学基金

52276150

2024

东南大学学报(自然科学版)
东南大学

东南大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.989
ISSN:1001-0505
年,卷(期):2024.54(2)
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