首页|非均质固化渣土的压缩特性与微观结构分析

非均质固化渣土的压缩特性与微观结构分析

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为探究不充分切削搅拌对换填层工程的影响,制备不同大小的渣土块,研究不同尺寸渣土块固化后的压缩特性,探讨磷石膏比例对非均质固化土性能的影响规律和作用机理,以实现磷石膏固废利用和降低固化剂能耗的目的.研究结果表明,水泥-磷石膏协同非均质固化渣土的压缩性显著降低,前期屈服应力提高至392 kPa,后随土块直径增加至7 mm而降低;随磷石膏掺量的增加,固化效果达到最优后发生下降,28 d龄期时的磷石膏最优质量分数为水泥的30%.固化剂水化产物在土块表面形成硬壳层作为承荷骨架;磷石膏与水泥水化产物反应生成膨胀性钙矾石部分填充块体间孔隙,降低整体压缩性能;过量磷石膏会产生硬壳层内应力,导致屈服应力降低.
Analysis on compression characteristics and microscopic structure of heterogeneously stabilized lumpy soils
To explore the influence of inadequate cutting and mixing on the replacement engineering,the lumpy wastes of different sizes were prepared to investigate the compression behavior of the heterogeneously stabilized lumpy waste.The influence and mechanism of phosphogypsum ratio on the performance of heteroge-neously stabilized lumpy soils were explored,in order to realize the utilization of phosphogypsum solid waste and reduce the energy consumption of solidifying agents.The results show that the compressibility of the ce-ment-phosphogypsum synergistic heterogeneously stabilized lumpy waste is significantly reduced,and the pre-yielding stress first increases to 392 kPa and then decreases as the lump diameter increases to 7 mm.The stabi-lization quality gradually reaches the optimum and then decreases as the content of phosphogypsum increases,and the optimal mass fraction of phosphogypsum at the age of 28 d is 30%of the cement.The hydration prod-ucts of the binder form a stiff-shell crust on the surface of the lumps,forming a force-bearing skeleton.The ettringite formed by the hydration reaction of phosphogypsum and cement's hydration products has remarkable expansibility,and partially fills the pores among lumpy wastes,thus reducing the compressibility.The exces-sive phosphogypsum will lead to internal stress of the stiff-shell layer,resulting in the reduction of preyielding stress.

lumpy wastecement-phosphogypsum binderheterogeneous stabilizationcompressibilitypreyi-elding stressmicrostructure

石修松、杨健、万星、邓永锋、丁建文

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河海大学岩土力学与堤坝工程教育部重点实验室,南京 210024

东南大学交通学院,南京 211189

废弃渣土 水泥-磷石膏固化剂 非均质固化 压缩特性 屈服应力 微观结构

国家自然科学基金面上资助项目国家自然科学基金面上资助项目河海大学高层次人才引进计划科研配套资助项目

5227834642272322522020212

2024

东南大学学报(自然科学版)
东南大学

东南大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.989
ISSN:1001-0505
年,卷(期):2024.54(5)