首页|不同热老化条件下XLPE热性能变化研究

不同热老化条件下XLPE热性能变化研究

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以商用110kV交联聚乙烯为研究对象,观察其在160℃热老化及冷热循环老化条件下的结晶形态、分子结构变化.采用热失重(thermogravimtric analyzer,TGA)、XRD(X-ray diffraction)、DSC(Differential Scanning Calorimetry)测试手段,分别对不同老化条件下交联聚乙烯的结晶度、热分解行为及热学性能变化进行表征.结果表明:交联聚乙烯的晶体劣化程度与热性能劣化规律基本一致,但冷热循环老化条件下的交联聚乙烯相较于160℃热老化条件下的试样,劣化持续时间更长、相同老化时间下劣化程度更小,归因于冷却阶段中交联聚乙烯在初始升温阶段经历再交联过程后,在降温阶段经历重结晶过程.
Study on the Change of Thermal Properties of XLPE Under Different Heat Aging Conditions
In this paper,commercial 110kV crosslinked polyethylene is used as the research object to observe its crystal morphology and molecular structure changes under the conditions of heat aging and hot and cold cycle aging at 160℃.Thermogravimtric analyzer(TGA),XRD(X-ray diffraction)and DSC(Differential Scanning Calorimetry)test methods are used to characterize the crystallinity,thermal decomposition behavior and thermal properties of cross-linked polyethylene under different aging conditions.The results show that the crystal deterioration degree of cross-linked polyethylene is basically the same as the deterioration law of thermal performance,but the deterioration duration of cross-linked polyethylene under the hot and cold cycle aging condition is longer and the degree of deteri-oration is smaller under the same aging time than that of the specimen under the heat aging condition of 160℃,which is attributed to the re-crosslinking process in the initial heating stage and the recrystallization process in the cooling stage after the re-crosslinking process in the cooling stage.

cross-linked polyethylenethermal agingthermal propertymolecular

王珏、徐磊、冯浩

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陕西新能联慧科技有限公司,陕西 西安,710000

陕西龙源建筑安装工程有限公司,陕西延安 727300

交联聚乙烯 热老化 热学性能 分子结构

2024

电气开关
沈阳电气传动研究所

电气开关

影响因子:0.281
ISSN:1004-289X
年,卷(期):2024.62(4)