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深部超临界地热条件下纯水的电阻和电导演变特征

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通过测定纯水在300~500 ℃和30~50 MPa条件下的电阻,揭示了纯水电阻和电导由亚临界区进入超临界区的变化特征.在此基础上,探讨了超临界水电阻和电导随温度和压力变化的演变机理.结果表明,纯水电导值在超临界点(374 ℃,22.1 MPa)附近具有涨落现象,具体表现为:(1)在亚临界区电导值与温度具有正相关关系,这是由于H+和OH-的极限当量电导之和随温度升高而上升所导致;(2)进入超临界区后电导值与温度具有负相关关系,这是由于水的密度和解离常数随温度上升而降低所导致.此外,固定温度条件下,纯水电导值与压力始终保持正相关关系.本次研究可为深部超临界地热资源地球物理勘探和解译提供基础数据.
Evolution characteristics of pure water resistance and conductance under deep supercritical geothermal conditions
The resistance of pure water was measured under 300~500 ℃ and 30~50 MPa to illuminate the evolution characteristics of pure water resistance and conductance from the subcritical to supercritical conditions.Furthermore,the evolution mechanism of the resistance and conductance with temperature and pressure is interpreted.The results indicate that the pure water conductance fluctuates near the supercritical point(374 ℃,22.1 MPa),which is as follows:(1)the conductance in the subcritical region has positively correlated with temperature,which is caused by the sum of the ultimate equivalent conductance of H+and OH-increasing with the increase of temperature;(2)the conductance has a negative correlation with temperature after entering the supercritical region,which is caused by the decrease of the density and ion product of water with the increase in temperature.In addition,there is a positive correlation between conductance and pressure at a constant temperature.This study provides basic data for geophysical exploration and interpretation of deep supercritical geothermal resources.

Supercritical geothermalHigh temperature and pressureResistanceElectric conductanceHydrothermal experiment

钟承昊、许天福、袁益龙、封官宏

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吉林大学地下水资源与环境教育部重点实验室,长春 130021

超临界地热 高温高压 电阻 电导 水热实验

国家自然科学基金

42130303

2024

地球物理学进展
中国科学院地质与地球物理研究所 中国地球物理学会

地球物理学进展

CSTPCD北大核心
影响因子:1.761
ISSN:1004-2903
年,卷(期):2024.39(2)