首页|焦化洗油污染地下水出露河段石油类污染物的扩散模拟与分析

焦化洗油污染地下水出露河段石油类污染物的扩散模拟与分析

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近年来突发石油类水环境污染事件频发,精准识别石油类污染物在水体的迁移规律成为了应急处置的关键.本文利用3EWATER水质模型,对喀斯特地貌下某焦化公司泄露洗油经地下水出露沟谷河道后,在水体中的迁移规律进行研究.结果表明:喀斯特地貌岩溶系统对石油类污染物有积累作用,降雨会导致水中污染物浓度显著增长;河流曼宁系数设为0.13时,模拟流速与水文站实测流速相关系数为0.92,模拟准确度高;距出露点3.4 km兴趣点断面的模拟浓度范围为0.05~15.3 mg/L,实测浓度范围为0.05~35.10 mg/L,决定系数为0.77;距出露点18 km兴趣点断面模拟浓度范围0.05~0.83 mg/L,实测浓度范围0.05~9.32 mg/L,相关系数降低到0.33.这说明洗油成因的石油类污染物因其化学成分复杂,在喀斯特自然河道水体中物化转化机制及运动规律具有特殊性.研究成果拓展了复杂情势水体和独特成因石油类污染水环境数值模拟应用,为掌握石油类污染峰团运移情况,科学采取应对措施提供参考.
Simulation and Analysis of Oil Pollutant Diffusion in River Affected by Coking Wash Oil Contaminated Groundwater
In recent years,there has been a frequent occurrence of sudden oil-related water pollution incidents.Accurately identifying the migration patterns of oil pollutants in water has become crucial for emergency response.This study uses the 3EWATER water quality model to investigate the migration patterns of leaked wash oil from a coking company in a karst landscape after it enters the groundwater and surfaces in valley river channels.The results indicate that the karst system accumulates oil pollutants and rainfall significantly increases pollutant concentrations in the water.When the Manning coefficient for the river is set to 0.13,the correlation coefficient between the simulated flow velocity and the measured flow velocity at the hydrological station is 0.92,indicating high simulation accuracy.At the point of interest 3.4 km from the exposure point,the simulated concentration range is 0.05-15.3 mg/L,while the measured concentration range is 0.05-35.10 mg/L,with a correlation coefficient of 0.77.At the point of interest 18 km from the exposure point,the simulated concentration range is 0.05-0.83 mg/L,while the measured concentration range is 0.05-9.32 mg/L,with the correlation coefficient decreases to 0.33.This reflects that oil pollutants from wash oil exhibit unique physical and chemical transformation mechanisms and movement patterns in the water bodies of natural karst rivers due to their complex chemical composition.The findings of this study expand the application of numerical simulation in complex water bodies and the unique oil pollution scenarios,providing a reference for understanding the migration of oil pollution peaks and scientifically implementing response measures.

leakage accidentcoal coking washing oilhydrodynamic simulationwater quality simulation

朱彬、黄代宽、徐磊、谢蔚嵩、安思危、王程程、龚效宇、张重乾、黎伟、朱令、叶樑锴、张少剑

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贵州省环境科学研究设计院,贵阳 550081

溢油事故 焦化洗油 水动力模型 水质模型

2024

地球与环境
中国科学院地球化学研究所

地球与环境

CSTPCD北大核心
影响因子:0.875
ISSN:1672-9250
年,卷(期):2024.52(6)