安全与环境工程2024,Vol.31Issue(1) :96-106,115.DOI:10.13578/j.cnki.issn.1671-1556.20221581

CaCl2与BaCl2复配对水泥浆抗负温劣化和硫酸盐侵蚀的试验研究

Experimental study on negative temperature deterioration and sulfate attack resistance of cement slurry by compounding CaCl2 and BaCl2

胡灿 杜军 万勇 刘天乐 杨国坤 曲波 郑少军 寇俊辉 倪晓阳
安全与环境工程2024,Vol.31Issue(1) :96-106,115.DOI:10.13578/j.cnki.issn.1671-1556.20221581

CaCl2与BaCl2复配对水泥浆抗负温劣化和硫酸盐侵蚀的试验研究

Experimental study on negative temperature deterioration and sulfate attack resistance of cement slurry by compounding CaCl2 and BaCl2

胡灿 1杜军 2万勇 3刘天乐 1杨国坤 1曲波 1郑少军 1寇俊辉 1倪晓阳1
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作者信息

  • 1. 中国地质大学(武汉)工程学院,湖北武汉 430074
  • 2. 湖北省应急管理宣传教育中心,湖北十堰 442522
  • 3. 湖北兴发化工集团股份有限公司,湖北 宜昌 443700
  • 折叠

摘要

随着我国"西部大开发"和"一带一路"发展战略的深入推动,冻土区施工日渐增多,负温劣化和硫酸盐侵蚀对水泥浆性能的负面影响给工程建设带来了安全隐患.通过-20 ℃恒温无预养水泥浆水化试验,利用XRD、SEM、TG、CT和力学测试等手段对水泥浆水化产物、孔隙结构、力学性质等进行分析,综合评价了 CaCl2-BaCl2复配使用对水泥浆在负温和硫酸盐环境下水化性能的影响.试验结果表明:相比于单一使用CaCl2,添加BaCl2不仅可以促进水泥浆水化程度,还可与SO42-反应,减少高硫型水化硫铝酸钙(又称钙矾石,AFt)的生成,提升水泥浆抗硫酸盐侵蚀能力;CaCl2-BaCl2复配使用时BaCl2的合理掺量为10wt%~15wt%,此时水泥浆具有相对最优的水化产物、孔隙结构和力学性质,其抗负温劣化和抗硫酸盐侵蚀能力也得到了显著提高.该研究结果可为冻土区工程建设提供理论参考和技术借鉴.

Abstract

With the in-depth promotion of China's"Western Development"and"Belt and Road"develop-ment strategies,construction in permafrost regions is increasing.The negative effects of negative tempera-ture degradation and sulfate attack on the performance of cement slurry have brought potential safety haz-ards to engineering construction.In this paper,the hydration products,pore structure and mechanical prop-erties of cement slurry were analyzed by XRD,SEM,TG,CT and mechanical test through the hydration test of cement slurry without precuring at-20 ℃.The effect of CaCl2-BaCl2 compound on the hydration performance of cement slurry under negative temperature and sulfate environment was comprehensively e-valuated.The experimental results show that compared with the single use of CaCl2,the addition of BaCl2 can not only promote the hydration degree of cement slurry,but also react with SO42-,reduce the formation of ettringite(also known as calcium aluminite,AFt),and improve the resistance of cement slurry to sulfate attack.When CaCl2-BaCl2 is used in combination,the reasonable dosage of BaCl2 is 10wt%-15wt%.At this time,the cement slurry has relatively optimal hydration products,pore structure and mechanical prop-erties,and its resistance to negative temperature degradation and sulfate attack is also significantly im-proved.The research results can provide theoretical reference and technical reference for engineering con-struction in frozen soil area.

关键词

水泥浆/负温劣化/硫酸盐侵蚀/CaCl2-BaCl2复配/水化性能评价/试验研究

Key words

cement slurry/negative temperature deterioration/sulfate attack/CaCl2-BaCl2 compound/hydra-tion performance evaluation/experimental investigation

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基金项目

国家重点研发计划项目(2022YFC3005904-4)

出版年

2024
安全与环境工程
中国地质大学

安全与环境工程

CSTPCDCSCD北大核心
影响因子:1.03
ISSN:1671-1556
参考文献量12
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