首页|广东某高速公路隧道衬砌混凝土腐蚀成因与规律研究

广东某高速公路隧道衬砌混凝土腐蚀成因与规律研究

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长期处于侵蚀性水环境中所引起的化学侵蚀是公路隧道混凝土的常见病害之一.这种侵蚀会导致混凝土耐久性下降,进而对隧道结构安全构成威胁并需要大量资金进行养护.然而,现有研究普遍缺乏工程实例依托,试验和模拟参数设置与工程实际的关联性较弱,难以准确、全面地反映现实中复杂侵蚀水环境下混凝土腐蚀的机制.为此,选取我国广东某高速公路隧道为工程实例,采用原位和实验室水化学指标测试、XRF测试手段确定混凝土化学侵蚀来源,并以隧道地下水渗流模拟试验复现化学侵蚀过程,研究混凝土的腐蚀成因、化学侵蚀规律和控制因素.结果表明:①隧道衬砌混凝土与低Ca2+、高HCO3-浓度的地下水接触、混合后发生钙溶蚀,形成了高pH值、高饱和的CaCO3 溶液及过饱和沉淀,并在地下水经裂隙快速喷出进入隧道的过程中,CO2分压下降促使CaCO3 进一步过饱和析出;②在隧道衬砌混凝土钙溶蚀初期,混凝土液相Ca(OH)2与地下水Ca2+浓度差较大,钙溶蚀速率较快,而随着钙溶蚀的进行,固相Ca(OH)2 持续被消耗且隧道排水中Ca2+浓度持续升高,与地下水中Ca2+浓度差缩小,钙溶蚀速率趋缓,最终在动水条件下达到动态平衡,隧道排水水化学特征维持相对稳定;③低Ca2+、高HCO3-浓度的地下水有利于混凝土的钙溶蚀和CaCO3过饱和析出沉淀,而过高或过低的地下水渗流流速(固液停留时间)均不利于相关化学反应的进行.
Study on the origins and laws of the concrete corrosion in a highway tunnel lining in Guangdong
Chemical corrosion arising from long-term exposure to aggressive water environment is one of the common diseases of highway tunnels.It will cause the failure of concrete durability,hence threating the safety of the highway tunnel structure,and large amounts of money is needed for maintenance.However,existing studies generally lack engineering projects in reality as research background which makes the experimental and simulation parameter settings disconnected from the actual engineering.As a result,it is hard to accurately and comprehensively reflect the corrosion mechanism of highway tunnels under an actual complex erosive water en-vironment.In this paper,we aim at study the origins,laws and controlling factors of concrete corrosion in high-way tunnels.In order to achieve this goal,we selected a highway tunnel in Guangdong as the research object,utilized in-situ and laboratory chemical index testing of water,XRF testing to determine chemical erosion sources of the highway tunnel and conducted groundwater seepage experiments to reproduce the chemical erosion pro-cess of concrete.The results are as follows:① Calcium leaching from cement hydrate of concrete while tunnel lining concrete contacts with the groundwater with low Ca2+and high HCO3-concentration,hence forming a strongly alkaline CaCO3 solution and supersaturated precipitation.In addition,the partial pressure drop of CO2 promotes the further supersaturated precipitation of CaCO3 during the rapid ejection of groundwater through cracks and entering the highway tunnel.② At the early stage of the calcium dissolution,due to the Ca2+concen-tration difference between the liquid phase in cement and groundwater,the Ca(OH)2 moves relatively fast into groundwater.As the calcium dissolution progresses,the solid-phase Ca(OH)2 of cement continues to be con-sumed and hence the Ca2+concentration in drainage water spikes to a high level.It results in the Ca2+concentra-tion gap becoming narrow and the calcium dissolution rate gradually dwindling.Finally,under hydrodynamic conditions,the calcium dissolution keeps a dynamic equilibrium and the chemical characteristics of drainage water remain relatively stable.③ Groundwater with low Ca2+and high HCO3-concentration is conducived to calcium dissolution of concrete and supersaturated precipitation of CaCO3.In addition,too high or low ground-water seepage velocity is not beneficial to the above reactions.

highway tunnelconcretecorrosion causecontrolling factorstunnel groundwater seepage simula-tion experiment

李云安、朱敦铭、田然、罗朝晖、黄惟琛

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中国地质大学(武汉)工程学院,湖北 武汉 430074

湖北省地质局水文地质工程地质大队,湖北 荆州 434020

中国地质大学(武汉)环境学院,湖北 武汉 430078

公路隧道 混凝土 腐蚀成因 控制因素 隧道地下水渗流模拟试验

2024

安全与环境工程
中国地质大学

安全与环境工程

CSTPCD北大核心
影响因子:1.03
ISSN:1671-1556
年,卷(期):2024.31(5)