安全与环境工程2025,Vol.32Issue(1) :263-272.DOI:10.13578/j.cnki.issn.1671-1556.20230863

长江江苏段地表水中典型抗生素赋存特征及来源分析

Occurrence characteristics and sources of typical antibiotics in surface water of Jiangsu section of the Yangtze River

张璐 刘伟 刘树洋 周亮 岳强 黄纯凯
安全与环境工程2025,Vol.32Issue(1) :263-272.DOI:10.13578/j.cnki.issn.1671-1556.20230863

长江江苏段地表水中典型抗生素赋存特征及来源分析

Occurrence characteristics and sources of typical antibiotics in surface water of Jiangsu section of the Yangtze River

张璐 1刘伟 1刘树洋 1周亮 1岳强 1黄纯凯1
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作者信息

  • 1. 江苏省环境科学研究院,江苏 南京 210036
  • 折叠

摘要

采用超高效液相色谱三重四级杆质谱法,对南京、泰州、苏州3个城市长江流域干流及入江支流断面和水源地水环境中7大类30种抗生素的赋存特征和来源进行了研究,并对流域内的医院、制药企业和城镇污水处理厂的废水展开调研.结果表明:各抗生素的检测浓度在ND(未检出)~7.79 ng/L之间,检出浓度最高的3类抗生素分别是氯霉素类、林可霉素类和磺胺类,其浓度依次为 59.48、55.14 和 30.87 ng/L,分别占抗生素浓度总和的37.5%、34.8%和19.5%;四环素类抗生素未被检出;在水处理设施的出水中检出大量喹诺酮类和大环内酯类抗生素,表明现有传统污水处理工艺对该类抗生素的去除能力有限.因此,未来应进一步关注高级氧化、生物强化及新型组合工艺技术的研发和应用.

Abstract

The occurrence characteristics and sources of 30 kinds of antibiotics in seven categories in the cross sections of main stream and tributaries of the Yangtze River in Nanjing,Suzhou and Taizhou were examined by ultra-high performance liquid chromatography(HPLC)triple quadrupole mass spectrometry.The results show that the detected concentration of each antibiotic ranges from ND(not detected)to 7.79 ng/L,the highest concentrations of chloramphenicols,lincomycins,and sulfonamides are 59.48、55.14 and 30.87 ng/L,accounting for 37.5%,34.8%,and 19.5%of total concentration of antibiotics,respectively.And no tetracyclines are detected.A large number of quinolones and macrolides residues are detected in the effluents of wastewater treatment facilities from hospitals,pharmaceutical enterprises and urban wastewater treatment plants,indicating that the existing traditional wastewater treatment processes have limited biodegradation ability for those antibiotics.Therefore,the long-term accumulation of antibiotics in the main stream and tributaries of Jiangsu section Yangtze River still has high ecological and health risks,and further attention should be paid to the development and application of advanced oxidation,biological enhanced treatment,and new combined treatment techniques in the future.

关键词

抗生素/长江江苏段/赋存特征/污染源/处理技术

Key words

antibiotic/Jiangsu section of the Yangtze River/occurrence characteristic/pollution source/treatment technology

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出版年

2025
安全与环境工程
中国地质大学

安全与环境工程

CSCD北大核心
影响因子:1.03
ISSN:1671-1556
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