首页|基于中红外吸收光谱的天然气泄漏CH4、C2H6痕量气体同步测量技术研究

基于中红外吸收光谱的天然气泄漏CH4、C2H6痕量气体同步测量技术研究

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为实现城镇燃气管网泄漏的高效检测,设计了基于中红外带间级联激光器和13m长光程气体池的CH4、C2 H6 双组分浓度测量传感器.该传感器利用激光控制器输出特定波长激光,覆盖CH4、C2 H6 吸收线,实现同步检测,通过维持气体池负压来避免水汽吸收对检测的影响.长时间性能测试表明,CH4、C2 H6 相对误差分别为 0.5%和 1.8%;通过Allan方差分析,系统在 327 s时,CH4 最小检测下限为1.31×10-9(体积分数),当积分时间为402 s时,C2 H6 最小检测下限可达0.02×10-9(体积分数),具备卓越的检测性能和稳定性.移动监测实验结果表明,天然气中CH4 与C2 H6 呈强线性相关性,皮尔森相关系数高达 0.999 133,为天然气泄漏的辨别提供了可靠依据.这一燃气检测技术在工程应用上具有重要价值.
Research on the Synchronous Measurement of CH4 and C2 H6 Trace Gases in Natural Gas Leaks Based on Mid-Infrared Absorption Spectrum
To efficiently detect leaks in urban gas networks,a two-component concentration measurement sensor for CH4and C2 H6 based on a mid-infrared interband cascade laser and a 13-meter long optical range gas cell is designed.The sensor emits a laser of specific wavelength,covering CH4 and C2 H6absorption lines for simultaneous detection,while preventing water vapor interference through gas cell negative pressure.Long-term tests reveal 0.5%and 1.8%relative errors for CH4 and C2 H6.Allan variance analysis shows a mini-mum detection limit of 1.31×10-9 for CH4 at 327 s and 0.02×10-9 for C2 H6 at 402 s integration time,demonstrating excellent stability.Mobile monitoring confirms a strong linear correlation(Pearson coefficient 0.999 133)between CH4 and C2 H6 in natural gas,offering a reliable basis for leakage identification.The proposed technology holds significant value in engineering applications.

methane-ethane two-component gas sensormid-infrared laser absorption spectroscopyPearson correlation coefficientnatural gas leakage

宋高峰、陈潇、吴胜平、刘婧婧、饶钊

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江苏省特种设备安全监督检验研究院,江苏 南京 210036

国家压力管道元件质量监督检测中心,江苏 南京 211162

东南大学能源与环境学院,江苏 南京 210096

甲烷乙烷双组分气体传感器 中红外激光吸收光谱 皮尔森相关系数 天然气泄漏

2024

电子器件
东南大学

电子器件

CSTPCD
影响因子:0.569
ISSN:1005-9490
年,卷(期):2024.47(6)