首页|可拉伸银纳米线透明导电膜的制备及性能研究

可拉伸银纳米线透明导电膜的制备及性能研究

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以银纳米线(AgNWs)为导电相,聚二甲基硅氧烷(PDMS)膜为基材,采用旋涂-转移法制备可拉伸银纳米线透明导电膜,即先将AgNWs均匀旋涂在聚对苯二甲酸乙二酯(polyethylene Terephthalate,PET)薄膜表面,然后转移到半干的PDMS膜表面,再经热处理获得可拉伸银纳米线透明导电膜(AgNWs/PDMS).研究了银纳米线的浓度、用量和尺寸以及旋涂层数对AgNWs/PDMS导电性、透光性、可拉伸性以及稳定性的影响;随着银纳米线浓度和用量的增加,AgNWs/PDMS膜的导电性和透光性下降.随着银纳米线直径下降,薄膜的透光性增加,但导电性下降.采用 0.2 mL的 2 mg/mL银纳米线(直径 60 nm,长度 25~30 μm)旋涂4 层所制备的薄膜在550 nm处的透光率为 72.5%,方阻为 32.94 Ω/□.同时,AgNWs/PDMS膜具有良好的柔韧性、弯折稳定性、可拉伸性和电稳定性.
Preparation and properties of stretchable silver nanowire transparent conductive film
Transparent and stretchable conductive film was prepared by spin-coating and transfer method with silver nanowires ( AgNWs) as conductive materials and polydimethylsiloxane ( PDMS) film as substrate. AgNWs were first uniformly spin coated on the surface of polyethylene terephthalate (PET) film,and transferred onto the surface of a semi dry polydimethylsiloxane (PDMS) film,which was then heat treated to obtain the stretchable and transparent conductive film. The concentration and content of AgNWs and spin coating times were studied to understand their effect on the conductivity,transmittance,stretchability,and stability of the AgNWs/PDMS film. The conductivity and transmittance of the AgNWs/PDMS film decrease as the concentration and amount of AgNWs increase. As the diameter of the AgNWs decreases,the transmittance increases,while the conductivity decreases. By spin-coating 4-layer of 0. 2 mL of 2 mg/mL AgNWs (diameter 60 nm,length 25-30 μm),the AgNWs/PDMS film has a transmittance of 72. 5% at 550 nm and a sheet resistance of 32. 94 Ω/□. Meanwhile,AgNWs/PDMS film exhibits excellent flexibility,bending stability,stretchability,and electrical stability.

silver nanowirestretchabletransparent conductive filmPDMSspin coating-transfer method

丁天磊、林晓彤、段安、王可、王悦辉

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电子科技大学中山学院 材料与食品学院,广东 中山 528402

银纳米线 可拉伸 透明导电膜 PDMS 旋涂-转移法

广东省教育厅创新团队项目广东省教育厅重点领域项目

2020KCXTD0302020ZDZX2027

2024

电子元件与材料
中国电子学会 中国电子元件行业协会 国营第715厂(成都宏明电子股份有限公司)

电子元件与材料

CSTPCD北大核心
影响因子:0.491
ISSN:1001-2028
年,卷(期):2024.43(6)
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