首页|GO/环氧丙烯酸涂层的制备及其在混凝土耐除冰盐腐蚀防护领域的应用

GO/环氧丙烯酸涂层的制备及其在混凝土耐除冰盐腐蚀防护领域的应用

Preparation of GO/epoxy acrylic coating and application in corrosion resistance of concrete to deicing salt

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以环氧树脂E-44和 3种丙烯酸类单体为原料,采用原位聚合法引入不同掺量的改性氧化石墨烯(GO)(KH560-GO(KGO)和A151-GO(AGO)),得到GO改性环氧丙烯酸(WEP)乳液,加入适量填料及助剂制得KGO/WEP和AGO/WEP防腐涂料并制成复合涂层.结果表明:加入KGO或AGO均可提高WEP涂层的热稳定性;其中 0.05wt%KGO/WEP的综合性能较优,该复合涂层的铅笔硬度为 5H,冲击强度≥50 cm,粘结强度 1.79 MPa,吸水率 1.06%,接触角 78.05°;紫外老化 1000 h后,色差变化较小为 0.75,光泽度保持较好为9.7;液体化学介质腐蚀 240 h后,涂层形貌仍保持良好;涂层氯离子渗透量为 0.34×10-3 mg/(cm2·d).将GO/WEP涂层涂装于混凝土砂浆试块表面,进行耐除冰盐冻融循环 40次后,涂层和混凝土试块的测试结果表明:0.05wt%KGO/WEP涂层综合性能较好,腐蚀后的涂层粘结强度最大为 1.91 MPa;砂浆试块的质量增长率为 1.46%,6 h氯离子电通量为 532 C,抗压强度损失率为 18.2%.该复合涂层可有效提高混凝土基材表面的耐除冰盐腐蚀性,对道路养护水平的提升具有重要的研究意义.
AGO/WEP and KGO/WEP anti-corrosion coating was prepared,using epoxy resin E-44 and three acrylic monomers as raw materials,modified by different dosages of graphene oxide(KH560/GO(KGO),A151/GO(AGO))under in-situ polymerization method.The results show that the addition of KGO or AGO can both improve the thermal performance of the composite coating.The comprehensive performance of 0.05wt%KGO/WEP is better,the pencil hardness of the composite coating is 5H,the impact strength is more than 50 cm,the bonding strength is 1.79 MPa,the water absorption rate is 1.06%,the contact angle is 78.05°,the color difference after 1000 h UV aging is 0.75,the gloss is maintained well at 9.7,the coating morphology is maintained well after 240 h of chemical resist-ance,and the chloride ion permeability of the coating is 0.34×10-3 mg/(cm2·d).The results show that the 0.05wt%KGO/WEP coating has good comprehensive performance and a maximum bond strength is 1.91 MPa after 40 salt freeze cycles.The mass growth rate is 1.46%,the chloride ion flux at 6 h is 532 C,the compressive strength loss is 18.2%.The composite coating can effectively improve the corrosion resistance of snow melting salt on the sur-face of concrete substrate,and has important research significance for improving the maintenance level of roads.

concretesalt freezing corrosiongraphene oxidewater-based acrylic paintanticorrosion coating

宋莉芳、赵丽轲、李开元、夏慧芸、牛艳辉

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长安大学 材料科学与工程学院,西安 710064

混凝土 盐冻腐蚀 氧化石墨烯 水性丙烯酸涂料 防腐涂层

陕西省重点研发计划国家自然科学基金长安大学中央高校基本科研业务费专项长安大学中央高校基本科研业务费专项

2023-YBGY-49652278427300102310301300102311404

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(3)
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