首页|二维Ti3C2修饰WO3/SrTiO3异质结复合材料及其光电化学阴极保护性能

二维Ti3C2修饰WO3/SrTiO3异质结复合材料及其光电化学阴极保护性能

Photoelectrochemical cathodic protection performance of two-dimensional Ti3C2-modified WO3/SrTiO3 heterojunction composites

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引入第二相材料构建异质结及加入助催化剂都可以有效提高半导体材料的光电化学性能.本文设计制备了WO3/SrTiO3 异质结复合材料并选用助催化剂Ti3C2 进行修饰,在模拟太阳光环境下通过光电化学阴极保护技术保护 304不锈钢(304 SS).结果表明:Ti3C2-WO3/SrTiO3 复合材料的光电化学阴极保护性能显著增强.将 304 SS与Ti3C2-WO3/SrTiO3 复合材料耦合,可将 304 SS的电位从-0.13 V转移到-0.42 V,并且三元复合材料产生的光电流密度是单独使用SrTiO3 的 7倍.在WO3/SrTiO3 界面上形成的异质结电场及助催化剂Ti3C2 的加入协同提高了光生电子和空穴的分离效率,提高了光电化学阴极保护性能.
The introduction of second-phase materials to construct heterojunctions and the addition of co-catalysts can effectively improve the photoelectrochemical performance of semiconductor materials.In this study,Ti3C2-WO3/SrTiO3 composites were designed and prepared to protect 304 stainless steel(304 SS)by photochemical cathodic protection technology in simulated sunlight environment.The results show that the photoelectrochemical cathodic protection performance of Ti3C2-WO3/SrTiO3 composites is significantly enhanced.Coupling 304 SS with Ti3C2-WO3/SrTiO3 composites transfers the potential of 304 SS from-0.13 V to-0.42 V,and the ternary composites produce a photocurrent density 7 times higher than SrTiO3 alone.The heterojunction electric field formed at the WO3/SrTiO3 interface and the addition of co-catalyst Ti3C2 synergistically improve the separation efficiency of photogenerated electrons and holes,and improve the photoelectrochemical cathodic protection performance.

heterojunctionsco-catalystTi3C2-WO3/SrTiO3compositesphotoelectrochemical cathodic protec-tion

苏新悦、王建省、赵英娜、庆达、曾雄丰

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华北理工大学 材料科学与工程学院,河北省无机非金属材料实验室,唐山 063210

河北省(唐山)陶瓷产业技术研究院,唐山 063007

异质结 助催化剂 Ti3C2-WO3/SrTiO3 复合材料 光电化学阴极保护

河北省自然科学基金钢铁联合基金唐山市科技局项目唐山市科技局项目

E202120900221130211D22130215H

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(3)
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