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低气压下民航客机机舱壁板材料的热解动力学

Pyrolysis kinetics of cabin panel materials for civil aircraft at low ambient pressure

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航空运输环境为低气压环境,低气压会对火灾的发生发展产生重大影响.为了探究低环境压力下民航客机机舱壁板材料的热解特性,利用热重分析仪对其热解特性进行研究.选取空客某型飞机玻璃纤维/酚醛树脂夹层板结构壁板材料(A壁板)和玻璃纤维/酚醛树脂层压板结构壁板材料(B壁板)作为研究对象,分别在四川广汉(96 kPa)和四川康定(61 kPa)进行研究.结果表明:随着压力的降低和升温速率的升高,A壁板、B壁板热分解反应的初始反应温度、终止反应温度及最大质量损失速率温度均略向高温方向移动.在15℃/min升温速率下,A壁板的上下树脂基面板由两个热解阶段组成,芳纶蜂窝芯只有一个热解阶段,且树脂基面板的初始分解温度约 182℃,明显小于芳纶蜂窝芯分解温度 413℃;B壁板热解分为两个阶段,初始热解温度约 258℃.采用Kissinger法、Flynn-Wall-Ozawa(FWO)法、Starink法和KAS法进行热解动力学分析,FWO法、Starink法和KAS法得到的表观活化能相近,低压下A壁板、B壁板表观活化能相对于常压下分别提高了大约 10.4%和 28.5%.而且 96 kPa环境下A壁板和B壁板的化学反应速率大约是 61 kPa环境下的1.9倍和1.2倍.
The air transport environment is a low pressure environment,which will have a significant impact on the occurrence and development of fire.In order to explore the pyrolysis characteristics of civil aircraft cabin panel materials under low environmental pressure,the pyrolysis characteristics of civil aircraft cabin panels were studied by the thermogravimetric analyzer.Selecting the glass fiber/phenolic resin sandwich panel structure panel material(A panel)and the glass fiber/phenolic resin laminated panel structure panel material(B panel)of a certain type of Airbus aircraft as the research objects,and studied in Guanghan(96 kPa)and Kangding(61 kPa)of Sichuan province,respectively.The results show that the initial reaction temperature,termination temperature and maxi-mum mass loss rate temperature of thermal decomposition of A and B panels move slightly to high temperature with the decrease of pressure and the increase of heating rate.At the heating rate of 15℃/min,the upper and lower resin base panel of A panel consists of two pyrolysis stages,and there is only one pyrolysis stage of aramid honey-comb core,and the initial decomposition temperature of the resin base panel is about 182℃,which is obviously lower than that of the aramid honeycomb core,while the pyrolysis temperature of B panel is divided into two stages and the initial pyrolysis temperature is about 258℃.The pyrolysis kinetics was analyzed by the Kissinger method,the Flynn-Wall-Ozawa method,the Starink method and the KAS method.The apparent activation energy obtained by the Flynn-Wall-Ozawa method,the Starink method and the KAS method is similar,and the apparent activation energy of A and B panels under low pressure increase by approximately 10.4%and 28.5%relative to that under normal pressure,respectively.And the chemical reaction rates of A panel and B panel in 96 kPa environment are about 1.9 and 1.2 times higher than that in 61 kPa environment.

low pressure environmentcivil aircraft wall panelglass fiber/phenolic resinthermal decomposi-tion characteristicspyrolysis kinetics

张晓宇、贾旭宏、丁思婕、田威、代尚沛、汤婧

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中国民用航空飞行学院 民航安全工程学院,广汉 618307

中国民用航空飞行学院 民机火灾科学与安全工程四川省重点实验室,广汉 618307

低压环境 民机壁板 玻璃纤维/酚醛树脂 热分解特性 热解动力学

四川省重点实验室揭榜挂帅项目中国民用航空飞行学院重点项目

XYKY2023011ZJ2021-01

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(4)
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