首页|碱处理对加捻竹纤维/环氧复合材料润湿性与拉伸失效的影响

碱处理对加捻竹纤维/环氧复合材料润湿性与拉伸失效的影响

Effect of alkali treatment on the wettability and tensile failure of twisted bamboo fiber/epoxy composites

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采用加捻竹纤维(TBF)为增强相、环氧树脂-酸酐体系为基体相,制备加捻竹纤维/环氧树脂(TBF/EP)复合材料,通过改变NaOH溶液浓度(1wt%~5wt%),研究碱处理对TBF/EP复合材料润湿性和拉伸失效的影响.采用SEM、表面张力测试、原位加载等纳米和微观试验手段,对纤维-树脂结合状态、润湿性能和拉伸力学特性进行了分析.结果表明:碱处理降低了纤维表面能和极性,使TBF与基体润湿力从0.45 mN降至 0.1 mN;3wt%NaOH溶液改性的TBF/EP复合材料含胶量降低至 62%,拉伸强度(TS)达到273.70 MPa,比未处理复合材料提高 178.64%;原位分析显示,TBF失效过程包括纤维断裂和纤维间滑移,而TBF/EP复合材料失效过程包括基体剪切屈服和纤维断裂,且随着浸润性提高,BF抑制屈服的效果增加.因此,TBF/EP复合材料的强度主要来源于纤维和界面的增强,受TBF与基体的浸润性、应力传递效果的影响.
The twisted bamboo fiber(TBF)was used as the reinforcement phase and the epoxy resin-anhydride sys-tem as the matrix phase to prepare the twisted bamboo fiber/epoxy resin(TBF/EP)composite.The effects of alkali treatment on the wettability and tensile failure of TBF/EP composites were investigated by varying the concentra-tion of NaOH solution(1wt%-5wt%).Nano-scale and micro-scale experimental techniques,such as SEM,surface tension testing,and in-situ loading,were employed to analyze the fiber-resin interface,wetting properties,and tensile mechanical properties of the composites.The results show that alkali treatment reduces the surface energy and polarity of the fibers,resulting in a decrease in the wetting force between TBF and the matrix from 0.45 mN to 0.1 mN.The TBF/EP composite modified with 3wt%NaOH solution exhibits a tensile strength(TS)of 273.70 MPa,which is 178.64%higher than that of the untreated composite.In-situ analysis reveals that the failure process of TBF involves fiber fracture and fiber sliding,while the failure process of the TBF/EP composite includes matrix shear yielding and fiber fracture.Moreover,as the wetting properties improve,the inhibitory effect of the fibers on matrix yielding increase.Therefore,the strength of the TBF/EP composite is mainly derived from the reinforcement of the fibers and the interface,which is influenced by wetting properties and stress transfer effect between TBF and matrix.

bamboo fibertwisted structurecompositewettabilityfailure mechanism

顾少华、李昊远、张文福、王翠翠、李明鹏、程海涛、王戈

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国际竹藤中心 竹藤科学与技术重点实验室,北京 100102

浙江省林业科学研究院,杭州 310023

竹纤维 加捻结构 复合材料 润湿性能 失效机制

国家自然科学基金国家重点研发计划

323719792022YFD2200903

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(4)
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