首页|各向异性纤维素纳米纤维/芳纶纳米纤维复合泡沫的制备与性能

各向异性纤维素纳米纤维/芳纶纳米纤维复合泡沫的制备与性能

Preparation and properties of anisotropic cellulose nanofiber/aramid nanofiber composite foam

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纤维素纳米纤维(CNF)泡沫材料因其轻质、可生物降解、可再生性以及优良的隔热性能等特点,在保温隔热领域备受关注.但是CNF泡沫存在力学性能差、热稳定性差、易燃等缺点,在一定程度限制了其实际应用.本文通过将CNF与芳纶纳米纤维(ANF)进行复合,通过冰模板法和冷冻干燥技术制备了具有各向异性结构的CNF/ANF复合泡沫.探究了ANF添加量和各向异性结构的引入对复合泡沫微观结构、力学性能、热稳定性和隔热性能的影响.结果表明,当CNF和ANF的质量比为 2∶1时,CNF/ANF复合泡沫具有超低的密度(12.25 mg/cm3)、良好的力学强度(纵向压缩强度为74.56 kPa)和优异的隔热性能(25.2 mW/(m·K)),此外,该复合泡沫还具有良好的热稳定性和自熄灭性能,这些特性赋予了其在保温隔热等领域更加广阔的应用前景.
Cellulose nanofibers(CNF)foam has gained attention in the field of thermal insulation due to its light-weight,biodegradable,renewable nature,and excellent insulation properties.However,CNF foam suffers from drawbacks such as poor mechanical properties,flammability,and limited thermal stability,which restrict their practical applications.This study prepared anisotropic CNF/ANF composite foam by introducing aramid nano-fibers(ANF)into nanocellulose fibers,using ice templating method combined with freeze-drying technique.The effects of ANF content and the introduction of anisotropic structure on the microstructure,mechanical properties,thermal stability,and thermal insulation performance of the composite foam were investigated.The results show that,when the mass ratio of CNF to ANF is 2∶1,the CNF/ANF composite foam exhibits an ultra-low density(12.25 mg/cm3),good mechanical strength(axial compressive strength of 74.56 kPa),and excellent thermal insula-tion performance(25.2 mW/(m·K)).Additionally,this composite foam also possesses good thermal stability and flame retardant properties,which endow it with broad prospects for applications in areas such as insulation and self-extinguishing property.

foamaramid nanofibercellulose nanofiberdirectional freeze-castingthermal insulationself-extinguishing

林旭、麦学妍、王钧、余雁、张雪霞

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福建农林大学 材料工程学院,福州 350002

泡沫材料 芳纶纳米纤维 纤维素纳米纤维 定向冷冻 隔热 自熄灭

国家自然科学基金青年基金福建省自然科学基金

320013812022J05035

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(6)