首页|赤泥/聚二甲基硅氧烷复合材料的制备及性能

赤泥/聚二甲基硅氧烷复合材料的制备及性能

Synthesis and properties of red mud/polydimethylsiloxane composites

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采用机械搅拌、真空磁力搅拌消泡和加热固化的方法,在柔性的聚二甲基硅氧烷(PDMS)中填充赤泥制备了赤泥/PDMS复合材料,并对复合材料的结构与形貌、力学性能和热性能进行了表征和分析.结果表明:赤泥作为交联节点和自润滑颗粒提高了复合材料的弹性模量、抗拉强度、邵氏硬度、冲击强度和摩擦磨损性能,其中,冲击强度的提高较显著,从 41.13 kJ·m-2 增大至 273.33 kJ·m-2,增加了 565%.此外,赤泥作为不可燃物也提高了复合材料的阻燃性能,极限氧指数从 25.7%增大至 34.7%,增加了 35%,进入难燃材料的范围(>27%).这有望扩宽这种硅酮材料的应用领域,同时为赤泥的资源化利用和新型赤泥/聚合物复合材料的研究提供参考.
Red mud/polydimethylsiloxane(PDMS)composites were prepared by filling red mud in flexible PDMS by mechanical stirring,vacuum magnetic stirring defoamination and heating curing.The structure,microstructure,mechanical and thermal properties of the composites were characterized and analyzed.The results show that:Red mud as a cross-linked node and self-lubricating particle improves the elastic modulus,tensile strength,hardness Shore,impact strength and friction and wear properties of the composites,among which the impact strength increases significantly from 41.13 kJ·m-2 to 273.33 kJ·m-2,an increase of 565%.In addition,red mud as a non-combustible also improves the flame retardant performance of the composites,the limiting oxygen index increases from 25.7%to 34.7%,an increase of 35%,into the range of refractory materials(>27%).This is expected to expand the application field of this silicone material,and provide a reference for the resource utilization of red mud and the research of new red mud/polymer composites.

red mudred mud utilizationpaddingcompositessiliconepolydimethylsilox

陆奔、李安敏、黄卓昉

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广西大学 资源环境与材料学院,南宁 530004

广西大学 省部共建特色金属材料与组合结构全寿命安全国家重点实验室,南宁 530004

广西大学 有色金属及材料加工新技术教育部重点实验室,南宁 530004

广西大学 广西高校高性能结构材料及热表加工重点实验室,南宁 530004

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赤泥 赤泥资源化 填料 复合材料 硅酮 聚二甲基硅氧烷

2021年中央引导地方科技发展资金专项2022年广西科技基地和人才专项广西重点研发计划项目

桂科ZY21195030桂科AD21238010桂科AB22080015

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(7)