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多层夹芯结构木塑复合材料阻燃与力学性能

Flame retardant and mechanical properties of wood-plastic composites with multi-layer sandwich structures

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针对传统膨胀石墨阻燃木塑复合材料(WPCs)阻燃剂添加量高、力学性能变差的问题,本文以杨木木粉(WF)、高密度聚乙烯(HDPE)、膨胀石墨(EG)与纳米二氧化硅(n-SiO2)为主要原料,通过层积热压工艺和结构优化设计制备了具有多层夹芯结构的阻燃增强木塑复合材料.采用锥形量热仪、垂直燃烧测试仪、极限氧指数(LOI)仪和万能力学试验机分别探究了单层、双层和三层夹芯结构对木塑复合材料阻燃和力学性能的影响.结果表明:相比于对照组(WPC-0),阻燃层中EG和增强层中n-SiO2 的含量分别为 10%和 5%时,双层和三层夹芯结构木塑复合材料的热释放速率和总热释放、烟释放速率和总烟释放均有显著降低,残余物质量明显提升.其中三层夹芯结构木塑复合材料(WPC-E3B)的LOI值由 20.8%提高至 30.6%,UL-94达到V-0 级.此外,相较于WPC-0,WPC-E3B的冲击强度提升了61.9%,拉伸与弯曲强度分别提高了16.2%和13.4%.
In order to solve the problems of high flame-retardant addition and deterioration of mechanical pro-perties in the modification of wood-plastic composites(WPCs)by traditional expandable graphite,flame-retardant reinforced wood-plastic composites with a multilayered sandwich structure were prepared by laminated hot pressing process and structure optimization design using poplar wood flour(WF),high-density polyethylene(HDPE),expandable graphite(EG)and nano-silicon dioxide(n-SiO2)as the main raw materials.And the appro-priate characterization and equipment such as cone calorimeter,vertical burner,limiting oxygen index(LOI)tester and mechanical testing machine were used to investigate the effects of single layer,double layer and triple layer sandwich structures on the flame retardant and mechanical properties of wood-plastic composites,respectively.The experimental results show that compared with the control wood-plastic composite(WPC-0),the multilayer structure wood-plastic composites exhibite significant reduction of heat release rate,total heat release,smoke pro-duction rate and total smoke production,and remarkable improvement of residue yield in the cone test when the contents of EG in the flame-retardant layer and n-SiO2 in the reinforcement layer are 10%and 5%,respectively.Among all the multilayer wood-plastic composites,WPC-E3B with a triple layer sandwich structure improves its LOI from 20.8%to 30.6%and passes the UL-94 test with a V-0 rating.Moreover,it also shows better mechanical proper-ties compared with WPC-0,such as a 61.9%increase in impact strength and 16.2%and 13.4%increases in tensile and flexural strength,respectively.

wood-plastic compositesexpandable graphitenano-silicasandwich structureflame retardancymechanical properties

郭雨佳、徐靖雯、陈文礼、樊奇、孙理超、王清文

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华南农业大学 生物基材料与能源教育部重点实验室,广州 510642

岭南现代农业科学与技术广东省实验室,广州 510642

木塑复合材料 可膨胀石墨 纳米二氧化硅 夹芯结构 阻燃性能 力学性能

广东省基础与应用基础研究基金广东省重点领域研发计划项目

2021A15150110142020B0202010008

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(7)