首页|微生物矿化抑制碱-硅酸反应的试验与机制探索

微生物矿化抑制碱-硅酸反应的试验与机制探索

Experimental and mechanism exploration of alkali-silica reaction inhibition by microbial mineralization

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碱-硅酸反应(ASR)是混凝土中碱性孔隙溶液和骨料中反应性非结晶SiO2 之间的反应,会导致混凝土膨胀和开裂及力学性能下降.本文基于巴氏芽孢杆菌微生物诱导碳酸钙沉淀(MICP)技术,采用不同处理次数及方式(表面处理潜在活性骨料及其制成的砂浆棒),综合评价MICP对ASR的抑制规律与机制.结果表明:MICP处理可以在骨料及砂浆棒表面形成具有黏附作用的致密CaCO3 层,从而阻止碱性离子和水的入侵,且抑制效果随处理次数的增多而变强;与对照组相比,处理砂浆棒时,力学性能最大提升了 13.8%,膨胀率下降了 35%;处理骨料时,由于表面CaCO3 层可同时阻隔孔隙溶液中已有及外部入侵的碱性离子与水分,其力学性能提升了 25.3%,膨胀率下降了 59.6%,具有更好的抑制效果.微观结构和成分分析表明,经MICP处理后骨料表面Si和Na原子比例分别下降了69.6%和 88.9%,表明ASR凝胶显著减少.
Alkali-silica reaction(ASR)is a reaction between alkaline pore solutions in concrete and reactive non-crystalline SiO2 in aggregates,which leads to expansion and cracking of the concrete,and degradation of mechani-cal properties.In this study,based on the microbial induced calcium carbonate precipitation(MICP)technique of Bacillus pasteurus,various treatment frequencies and methods,including surface treatments of potentially active aggregates and mortar bars made by them,to comprehensively evaluate the inhibition law and mechanism of MICP on ASR.The results showed that the MICP treatment could form a dense CaCO3 layer with adhesive effect on the surface of aggregates and mortar bars,thus preventing the intrusion of alkaline ions and water,and the inhibiting effect became stronger with the treatment numbers.Compared with the control group,the maximum increase in mechanical properties of 13.8%,and the decrease in expansion rate of 35%were observed when the mortar bars were treated.When treating the aggregate,the mechanical properties were improved by 25.3%and the expansion rate was reduced by 59.6%with a better inhibition effect,as the surface CaCO3 layer could simultaneously block the alkaline ions and water existing in the pore solution and invading from outside.Microstructural and compositional analyses showed that the proportion of Si and Na atoms on the aggregate surface decreased by 69.6%and 88.9%,respectively,after treatment,indicating a significant reduction in the ASR gel.

MICPalkali-silica reactionJinping sandstonemechanical propertiesexpansion rate

郑玉龙、林鸿儒、陆春华、王景全

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江苏大学 土木工程与力学学院,镇江 212013

MICP 碱-硅酸反应 锦屏砂岩 力学性能 膨胀率

国家自然科学基金项目国家自然科学基金项目江苏省博士后科研资助计划江苏大学高级人才基金

52108147518783192020Z35020JDG19

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(8)